Synthesis and characterization of Ge2{Sn(X)A#}3 and Ga2{Ge(X)Ar#}3 (Ar# = C6H3-2,6-Mes2), X = (Cl/I):: Rare examples of mixed heavier group 14/14, 13/14 element clusters

被引：43

作者：

Richards, AF ^{[1
]}

Brynda, M ^{[1
]}

Power, PP ^{[1
]}

机构：

[1] Univ Calif Davis, Dept Chem, Davis, CA 95616 USA

来源：

ORGANOMETALLICS | 2004年 / 23卷 / 17期

关键词：

D O I：

10.1021/om0497137

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of (ArECl)-E-# (Ar-# = C6H3-2,6-Mes(2); E = Ge or Sn) with 1 equiv of the reducing agent KC8 or 'GaI' led to the isolation and characterization of the two new main group clusters Ge-2{Sn(X)Ar-#}(3), 1, and Ga-2{Ge(X)Ar-#}(3), 2 (X = Cl or Cl/I), which have trigonal bypyramidal Ge2Sn3 or Ga2Ge3 frameworks. Cluster 1 is a singlet biradicaloid, whereas 2 is a very rare heavier group 13/14 element cluster, and the first with a Ga/Ge framework.

引用

页码：4009 / 4011

页数：3

共 50 条

[41] Yttrium complexes incorporating the chelating diamides {ArN(CH2)xNAr}2- (Ar = C6H3-2,6-iPr2, x=2, 3) and their unusual reaction with phenylsilane
Avent, AG
Geoffrey, F
Cloke, N
Elvidge, BR
Hitchcock, PB
DALTON TRANSACTIONS, 2004, (07) : 1083 - 1096
[42] Alloying and Properties of C14-NbCr2 and A15-Nb3X (X = Al, Ge, Si, Sn) in Nb-Silicide-Based Alloys
Tsakiropoulos, Panos
MATERIALS, 2018, 11 (03):
[43] Synthesis and characterization of (THF)3Li(NC)Cu(C6H3-2,6-MeS2) and Br(THF)2Mg (C6H3-2,6-Trip2) (Mes = C6H2-2,4,6-Me3; Trip = C6H2-2,4,6-i-Pr3):: The structures of a monomeric lower-order lithium organocyanocuprate and a bulky terphenyl grignard reagent in the solid state
Hwang, CS
Power, PP
BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2003, 24 (05) : 605 - 609
[44] Synthesis, characterization and comparison of group 14 pyrrolides and indolides Ph3MX (M = Si, Ge, Sn; X = C4H4N, C8H6N)
Poisson, Joel
Wharf, Ivor
Bohle, D. Scott
Barsan, Mirela M.
Gu, Yuxuan
Butler, Ian S.
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2010, 695 (23) : 2557 - 2561
[45] Gel combustion synthesis of La x Gd14-x B6Ge2O34 (x=3 and 4) codoped with Yb3+-Er3+ and Yb3+-Tm3+ active ions
Krut'ko, V. A.
Komova, M. G.
Novikova, S. A.
Pominova, D. V.
INORGANIC MATERIALS, 2015, 51 (12) : 1270 - 1276
[46] The first mixed-valent aAntimony(III/V) oxo clusters (2,6-Mes2C6H3Sb)2(ClSb)4O8 and (2,6-Mes2C6H3Sb)4(ClSb)4(HOSb)2O14
Beckmann, Jens
Heek, Timm
Takahashi, Masashi
ORGANOMETALLICS, 2007, 26 (15) : 3633 - 3635
[47] Syntheses and structures of [Sn{NR}(2){Sn(mu-NMe2)}(2)]: Model intermediates in the formation of imido group 14 cages and rings [R = 2,6-pr(2)(i)C(6)H(3) (Dipp), 2,4,6-Me3C6H2 (Mes)]
Allan, RE
Beswick, MA
Coggan, GR
Raithby, PR
Wheatley, AEH
Wright, DS
INORGANIC CHEMISTRY, 1997, 36 (23) : 5202 - 5205
[48] SYNTHESIS AND CHARACTERIZATION OF ALKYLALUMINUM IMINE COMPLEXES - THE X-RAY CRYSTAL-STRUCTURE OF [(C6H3-2,6-(CH3)2)CH=NAL(I-C4H9)2]2
JENSEN, JA
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 456 (02) : 161 - 166
[49] SUBVALENT GROUP-14 METAL-COMPOUNDS .11. COMPLEXES WITH GROUP-14 METAL IRON BONDS - THE SYNTHESIS AND CHARACTERIZATION OF THE COMPLEXES [FECP(CO)2(M(X)R2)] (R = CH(SIME3)2, CP = ETA-C5H5, M = SN AND X = H, F, CL, BR, I, OR OME, OR M = PB AND X = I)
LAPPERT, MF
MCGEARY, MJ
PARISH, RV
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 373 (01) : 107 - 117
[50] TRIARYL-SILYL, TRIARYL-GERMYL, AND TRIARYL-STANNYL RADICALS.MAR3 (M=SI, GE, OR SN AND AR=2,4,6-ME3C6H2) AND .GE(2,6-ME2C6H3)3 - SYNTHESIS AND ELECTRON-SPIN-RESONANCE STUDIES
GYNANE, MJS
LAPPERT, MF
RILEY, PI
RIVIERE, P
RIVIEREBAUDET, M
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1980, 202 (01) : 5 - 12

← 1 2 3 4 5 →