Synthesis and characterization of Ge2{Sn(X)A#}3 and Ga2{Ge(X)Ar#}3 (Ar# = C6H3-2,6-Mes2), X = (Cl/I):: Rare examples of mixed heavier group 14/14, 13/14 element clusters

被引：43

作者：

Richards, AF ^{[1
]}

Brynda, M ^{[1
]}

Power, PP ^{[1
]}

机构：

[1] Univ Calif Davis, Dept Chem, Davis, CA 95616 USA

来源：

ORGANOMETALLICS | 2004年 / 23卷 / 17期

关键词：

D O I：

10.1021/om0497137

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of (ArECl)-E-# (Ar-# = C6H3-2,6-Mes(2); E = Ge or Sn) with 1 equiv of the reducing agent KC8 or 'GaI' led to the isolation and characterization of the two new main group clusters Ge-2{Sn(X)Ar-#}(3), 1, and Ga-2{Ge(X)Ar-#}(3), 2 (X = Cl or Cl/I), which have trigonal bypyramidal Ge2Sn3 or Ga2Ge3 frameworks. Cluster 1 is a singlet biradicaloid, whereas 2 is a very rare heavier group 13/14 element cluster, and the first with a Ga/Ge framework.

引用

页码：4009 / 4011

页数：3

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