An Alkene-Forming Cascade Reaction En Route to 2,2′-Bi(glycerol)

被引：0

作者：

Li, Xiaoxun ^{[1
]}

Livant, Peter D. ^{[1
]}

Chen, Jianjun ^{[2
]}

机构：

[1] Auburn Univ, Dept Chem & Biochem, Auburn, AL 36849 USA

[2] Southern Med Univ, Sch Pharmaceut Sci, Guangdong Prov Key Lab New Drug Screening, Guangzhou, Guangdong, Peoples R China

来源：

SYNLETT | 2018年 / 29卷 / 13期

关键词：

cascade reaction; alkenes; olefins; 2-2 '-bi(glycerol); hexaalcohol; SODIUM HYDRIDE; REDUCING AGENT; REDUCTION; OLEFINS;

D O I：

10.1055/s-0037-1610037

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Synthesis of 2,3-bis(hydroxymethyl)butane-1,2,3,4-tetraol is of great interest because of its utility as a potential precursor to new dendrimers, in the preparation of unnatural lipids, and in the synthesis of open-framework coordination polymers. Synthesis of this new six-hydroxyl compound is achieved in four steps from commercially available starting materials. In this process, a new olefin-forming cascade reaction was discovered.

引用

页码：1769 / 1772

页数：4

共 50 条

[41] REACTION OF DIAZO-COMPOUNDS WITH AZO-COMPOUNDS .9. REACTION OF 2,2'-AZOPYRIDINE AND 2,2'-AZOQUINOLINE WITH DIAZOALKANES
FAHR, E
MARKERT, J
PELZ, N
[J]. ANNALEN DER CHEMIE-JUSTUS LIEBIG, 1973, (12): : 2088 - 2099
[42] Gold-Catalyzed Cascade Reaction of β-(2-Aminophenyl)-α,β-ynones with Ynamides: A Sequential Route to Polysubstituted 2-Aminoquinolines
Rode, Navnath D.
Arcadi, Antonio
Di Nicola, Antonella
Marinelli, Fabio
Michelet, Veronique
[J]. ORGANIC LETTERS, 2018, 20 (17) : 5103 - 5106
[43] En route to inherently chiral tetraoxacalix[2]arene[2]triazines
Hou, Bao-Yong
Zheng, Qi-Yu
Wang, De-Xian
Wang, Mei-Xiang
[J]. TETRAHEDRON, 2007, 63 (44) : 10801 - 10808
[44] A new route to 2,2′,3,3′-tetrasubstituted binaphthyls
Widhalm, Michael
Aichinger, Christian
Mereiter, Kurt
[J]. TETRAHEDRON LETTERS, 2009, 50 (20) : 2425 - 2429
[45] Modified polyoxometalate: a novel monocapped bi-supporting and reduced α-Keggin structure {PMo12O40[Cu(2,2′-bpy)]}[Cu(2,2′-bpy)(en)(H2O)]2
Lu, Yu-Kun
Li, Ya-Ping
Yang, Ling-Yu
Wang, Wen-Hong
Pan, Yuan
Yan, Wen-Fu
Liu, Yun-Qi
[J]. ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2019, 75 : 1344 - +
[46] COMPLEXES OF 2,2'-BI-2-IMIDAZOLINE WITH TRANSITION METAL IONS
WANG, JC
BAUMAN, JE
[J]. INORGANIC CHEMISTRY, 1965, 4 (11) : 1613 - &
[47] THE REACTION OF 2,2'-BIPYRIDYL WITH DIMOLYBDENUM TETRAACETATE DERIVATIVES
GUNALE, AS
CHRISTOU, G
[J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1992, 204 : 108 - INOR
[48] 2,2-DICHLORO-2-ARYLTHIOETHANALS IN REFORMATSKII REACTION
SHCHEPIN, VV
CHUPRIKOVA, TY
PETUKHOVA, IY
[J]. ZHURNAL ORGANICHESKOI KHIMII, 1991, 27 (08): : 1796 - 1797
[49] Cascade reaction and synthesis of bicyclo[2,2,2]octenones
Li Nian-Guang
Wang Jin-Xin
You Qi-Dong
Chu Gang
Guo Qing-Long
[J]. CHINESE JOURNAL OF CHEMISTRY, 2008, 26 (02) : 363 - 367
[50] An efficient, easy route for the synthesis of 2,2′:6′,2"-terpyridine 1′-oxides
Fallahpour, RA
Neuburger, N
[J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2001, 2001 (10) : 1853 - 1856

← 1 2 3 4 5 →