Graphene Oxide: An Efficient Acid Catalyst for Alcoholysis and Esterification Reactions

被引：92

作者：

Zhu, Shanhui ^{[1
]}

Chen, Chengmeng ^{[1
,2
]}

Xue, Yanfeng ^{[1
,3
]}

Wu, Jianbing ^{[1
,3
]}

Wang, Jianguo ^{[1
]}

Fan, Weibin ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China

[2] Chinese Acad Sci, Inst Coal Chem, Key Lab Carbon Mat, Taiyuan 030001, Peoples R China

[3] Univ Chinese Acad Sci, Beijing 100039, Peoples R China

来源：

CHEMCATCHEM | 2014年 / 6卷 / 11期

基金：

中国国家自然科学基金;

关键词：

alcoholysis; biofuels; esterification; graphene oxide; heterogeneous catalysis; FURFURYL ALCOHOL; ETHYL LEVULINATE; SOLID ACID; GRAPHITE OXIDE; CONVERSION; CELLULOSE; HETEROPOLYACIDS; CARBOCATALYST; HYDROLYSIS; GLYCEROL;

D O I：

10.1002/cctc.201402574

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Evidence is presented for graphene oxide (GO), prepared by modified Hummers method, as a highly active, selective and reusable solid-acid catalyst for the production of alkyl levulinates via alcoholysis or esterification. 95.5% yield of ethyl levulinate was achieved by GO in furfuryl alcohol alcoholysis. Moreover, the surface SO3H groups were identified as the primary active sites, while the surface carboxyl groups worked synergistically to adsorb furfuryl alcohol.

引用

页码：3080 / 3083

页数：4

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