Copper oxide–graphene oxide nanocomposite: efficient catalyst for hydrogenation of nitroaromatics in water

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作者
Kaiqiang Zhang
Jun Min Suh
Tae Hyung Lee
Joo Hwan Cha
Ji-Won Choi
Ho Won Jang
Rajender S. Varma
Mohammadreza Shokouhimehr
机构
[1] Seoul National University,Department of Materials Science and Engineering, Research Institute of Advanced Materials
[2] Korea Institute of Science and Technology (KIST),Center for Electronic Materials
[3] Korea Institute of Science and Technology (KIST),Small & Medium Enterprises Support Center
[4] Faculty of Science,Regional Centre of Advanced Technologies and Materials
[5] Palacky University in Olomouc,undefined
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Copper oxide; Graphene oxide; Hydrothermal; Hydrogenation; Synergistic effect;
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摘要
A low-cost nanocomposite catalyst containing copper oxide (CuO) nanoparticles (NPs) on graphene oxide (GO) was fabricated by a facile hydrothermal self-assembly process. The segregated CuO NPs and GO exhibited negligible catalytic activities for the reduction of nitroaromatics. However, their hybrid composite accomplished facile reduction with high conversions for several substituted nitroaromatics in aqueous NaBH4 solution; synergetic coupling effect of CuO NPs with GO in the nanocomposite catalyst provided excellent catalytic activity. The nanocomposite catalyst could be separated from the reaction mixture and recycled consecutively.
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