Cobalt(III)-catalysed C-H allylation with vinylaziridines

被引：24
|
作者：
Kong, Lingyu [1 ]
Biletskyi, Bohdan [1 ]
Nuel, Didier [1 ]
Clavier, Herve [1 ]
机构：
[1] Aix Marseille Univ, CNRS, Cent Marseille, ISm2 UMR 7313, F-13397 Marseille, France
来源：
ORGANIC CHEMISTRY FRONTIERS | 2018年 / 5卷 / 10期
关键词：
BOND FUNCTIONALIZATION; COBALT CATALYSIS; ACTIVATION; ARENES; AMIDATION; COMPLEX; OLEFINS; CARBON; RINGS; TOOL;
D O I：
10.1039/c8qo00173a
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A cobalt-catalysed C-H allylation of aromatic and heteroaromatic compounds with vinylaziridines is described. This transformation occurring under mild reaction conditions proceeds through C-H activation, carbon-carbon double bond insertion and beta-nitrogen elimination. Its scope and limitations have been investigated and a synthetic application of products has been achieved.
引用
收藏
页码：1600 / 1603
页数：4
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