Cobalt(III)-catalysed C-H allylation with vinylaziridines

被引：24

作者：

Kong, Lingyu ^{[1
]}

Biletskyi, Bohdan ^{[1
]}

Nuel, Didier ^{[1
]}

Clavier, Herve ^{[1
]}

机构：

[1] Aix Marseille Univ, CNRS, Cent Marseille, ISm2 UMR 7313, F-13397 Marseille, France

来源：

ORGANIC CHEMISTRY FRONTIERS | 2018年 / 5卷 / 10期

关键词：

BOND FUNCTIONALIZATION; COBALT CATALYSIS; ACTIVATION; ARENES; AMIDATION; COMPLEX; OLEFINS; CARBON; RINGS; TOOL;

D O I：

10.1039/c8qo00173a

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A cobalt-catalysed C-H allylation of aromatic and heteroaromatic compounds with vinylaziridines is described. This transformation occurring under mild reaction conditions proceeds through C-H activation, carbon-carbon double bond insertion and beta-nitrogen elimination. Its scope and limitations have been investigated and a synthetic application of products has been achieved.

引用

页码：1600 / 1603

页数：4

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