Heavy ion irradiation-induced microstructural evolution in pyrochlore Lu2Ti2O7 at room temperature and 723 K

被引：10
|
作者：
Xie, Q. R. [1 ]
Zhang, J. [1 ]
Dong, X. N. [1 ]
Guo, Q. X. [1 ]
Li, N. [1 ]
机构：
[1] Xiamen Univ, Coll Energy, Xiamen 361005, Fujian, Peoples R China
来源：
JOURNAL OF SOLID STATE CHEMISTRY | 2015年 / 231卷
基金：
中国国家自然科学基金;
关键词：
Phase transformation; Nano-crystal; Ion irradiation; PHASE; AMORPHIZATION; CERAMICS; DAMAGE;
D O I：
10.1016/j.jssc.2015.08.005
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Polycrystalline pyrochlore Lu2Ti2O7 pellets were irradiated with 600 key Kr3+ at room temperature and 723 K to a fluence of 4 x 10(15) ions/cm(2), corresponding to an average ballistic damage dose of 10 displacements per atom in the peak damage region. Irradiation-induced microstructural evolution was examined by grazing incidence X-ray diffraction, and cross-sectional transmission electron microscopy. Incomplete amorphization was observed in the sample irradiated at room temperature due to the formation of nano-crystal which has the identical structure of pyrochlore, and the formation of nano-crystal is attributed to the mechanism of epitaxial recrystallization. However, an ordered pyrochlore phase to a swelling disordered fluorite phase transformation is occurred for the Lu2Ti2O7 sample irradiated at 723 K, which is due to the disordering of metal cations and anion vacancies. (C) 2015 Elsevier Inc. All rights reserved.
引用
收藏
页码：159 / 162
页数：4
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