Iron-catalyzed enediene carbocyclizations. The total synthesis of (-)-gibboside

被引：11
|
作者：
Takacs, JM [1 ]
Vayalakkada, S [1 ]
Mehrman, SJ [1 ]
Kingsbury, CL [1 ]
机构：
[1] Univ Nebraska, Dept Chem, Lincoln, NE 68588 USA
来源：
TETRAHEDRON LETTERS | 2002年 / 43卷 / 46期
基金：
美国国家卫生研究院;
关键词：
D O I：
10.1016/S0040-4039(02)01662-3
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The first total synthesis of (-)-gibboside is reported. The route features a novel iron-catalyzed carbocyclization as the key step for the construction of the cis,trans,cis-tetrasubstituted cyclopentane core. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：8417 / 8420
页数：4
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