An (8,3)-a 3D coordination network and concomitant three-connected supramolecular isomers

被引：22
|
作者：
Luisi, Brian S.
Kravtsov, Victor Ch.
Moulton, Brian D. [1 ]
机构：
[1] Brown Univ, Dept Chem, Providence, RI 02906 USA
[2] Moldavian Acad Sci, Inst Appl Phys, MD-2028 Kishinev, Moldova
来源：
CRYSTAL GROWTH & DESIGN | 2006年 / 6卷 / 10期
关键词：
D O I：
10.1021/cg060534x
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An unprecedented (8,3)-a 3D coordination network was synthesized using crystal engineering strategies as one of three concomitant supramolecular isomers of the general formula [Cu-2(tae)(bipy)(2)]center dot 2NO(3)(-)center dot xS (bipy) 4,4'-bipyridine; tae = dibasic tetraacetylethane; S = solvent: H2O/MeOH). The (8,3)-a network yields optically active single crystals with 58% solvent-accessible volume, despite 4-fold interpenetration.
引用
收藏
页码：2207 / 2209
页数：3
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