Supramolecular fibers from a liquid crystalline octa-substituted copper phthalocyanine

被引:38
|
作者
Osburn, EJ
Schmidt, A
Chau, LK
Chen, SY
Smolenyak, P
Armstrong, NR
OBrien, DF
机构
[1] UNIV ARIZONA,DEPT CHEM,CARL S MARVEL LABS,TUCSON,AZ 85721
[2] MAX PLANCK INST POLYMER RES,D-55128 MAINZ,GERMANY
关键词
D O I
10.1002/adma.19960081113
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Supramolecular fibers-bundles of individual strands-result room the self-assembly of a novel octa-substituted copper phthalocyanine with benzyloxyethoxy side chains. The synthesis and self-assembly of the fibers are described and results from microscopy and X-ray characterization presented. It is shown that incorporation of aromatic groups in the side chains of phthalocyanines favors discotic mesophases with extended thermal stability, in addition to promoting the formation of supramolecular fibers.
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页码:926 / &
页数:4
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