Palladium/Norbornene Cooperative Catalysis

被引：382
|
作者：
Wang, Jianchun [1 ]
Dong, Guangbin [1 ]
机构：
[1] Univ Chicago, Dept Chem, 5735 S Ellis Ave, Chicago, IL 60637 USA
来源：
CHEMICAL REVIEWS | 2019年 / 119卷 / 12期
关键词：
C-H FUNCTIONALIZATION; ALKYLATION-ALKENYLATION REACTIONS; SUBSTITUTED ARYL IODIDES; TETRASUBSTITUTED HELICAL ALKENES; ONE-STEP SYNTHESIS; TOSYLHYDRAZONE INSERTION REACTION; CONCOMITANT ORTHO-ALKYLATION; RIGID LADDER POLYMERS; EFFICIENT SYNTHESIS; CATELLANI REACTION;
D O I：
10.1021/acs.chemrev.9b00079
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Palladium/norbornene cooperative catalysis has emerged as a distinct approach to construct polyfunctionalized arenes from readily available starting materials. This Review provides a comprehensive overview of this field, including the early stoichiometric investigations, catalytic reaction developments, as well as the applications in the syntheses of bioactive compounds and polymers. The section of catalytic reactions is divided into two parts according to the reaction initiation mode: Pd(0)-initiated reactions and Pd(II)-initiated reactions.
引用
收藏
页码：7478 / 7528
页数：51
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