Palladium/Norbornene Cooperative Catalysis

被引：382
|
作者：
Wang, Jianchun [1 ]
Dong, Guangbin [1 ]
机构：
[1] Univ Chicago, Dept Chem, 5735 S Ellis Ave, Chicago, IL 60637 USA
来源：
CHEMICAL REVIEWS | 2019年 / 119卷 / 12期
关键词：
C-H FUNCTIONALIZATION; ALKYLATION-ALKENYLATION REACTIONS; SUBSTITUTED ARYL IODIDES; TETRASUBSTITUTED HELICAL ALKENES; ONE-STEP SYNTHESIS; TOSYLHYDRAZONE INSERTION REACTION; CONCOMITANT ORTHO-ALKYLATION; RIGID LADDER POLYMERS; EFFICIENT SYNTHESIS; CATELLANI REACTION;
D O I：
10.1021/acs.chemrev.9b00079
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Palladium/norbornene cooperative catalysis has emerged as a distinct approach to construct polyfunctionalized arenes from readily available starting materials. This Review provides a comprehensive overview of this field, including the early stoichiometric investigations, catalytic reaction developments, as well as the applications in the syntheses of bioactive compounds and polymers. The section of catalytic reactions is divided into two parts according to the reaction initiation mode: Pd(0)-initiated reactions and Pd(II)-initiated reactions.
引用
收藏
页码：7478 / 7528
页数：51
相关论文
共 50 条
  • [21] Redox-Neutral ortho Functionalization of Aryl Boroxines via Palladium/Norbornene Cooperative Catalysis
    Li, Renhe
    Liu, Feipeng
    Dong, Guangbin
    CHEM, 2019, 5 (04): : 929 - 939
  • [22] Sulfenamide-enabled ortho thiolation of aryl iodides via palladium/norbornene cooperative catalysis
    Li, Renhe
    Zhou, Yun
    Yoon, Ki-Young
    Dong, Zhe
    Dong, Guangbin
    NATURE COMMUNICATIONS, 2019, 10 (1)
  • [23] Sulfenamide-enabled ortho thiolation of aryl iodides via palladium/norbornene cooperative catalysis
    Renhe Li
    Yun Zhou
    Ki-Young Yoon
    Zhe Dong
    Guangbin Dong
    Nature Communications, 10
  • [24] Structurally Modified Norbornenes: A Key Factor to Modulate Reaction Selectivity in the Palladium/Norbornene Cooperative Catalysis
    Li, Renhe
    Dong, Guangbin
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2020, 142 (42) : 17859 - 17875
  • [25] Rapid Access to Multisubstituted Acrylamides from Cyclic Ketones via Palladium/Norbornene Cooperative Catalysis
    Wu, Zhao
    Dong, Guangbin
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2022, 61 (17)
  • [26] Enantioselective Assembly of Ferrocenes with Axial and Planar Chiralities via Palladium/Chiral Norbornene Cooperative Catalysis
    Ye, Jinxiang
    Li, Lisha
    You, Yiming
    Jiao, Chengkang
    Cui, Ziyang
    Zhang, Yabin
    Jia, Shihu
    Cong, Hengjiang
    Liu, Shanshan
    Cheng, Hong-Gang
    Zhou, Qianghui
    JACS AU, 2023, 3 (02): : 384 - 390
  • [27] Exception to the ortho Effect in Palladium/Norbornene Catalysis
    Larraufie, Marie-Helene
    Maestri, Giovanni
    Beaume, Aurore
    Derat, Etienne
    Ollivier, Cyril
    Fensterbank, Louis
    Courillon, Christine
    Lacote, Emmanuel
    Catellani, Marta
    Malacria, Max
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (51) : 12253 - 12256
  • [28] Polymerization via Pd/norbornene cooperative catalysis
    Yoon, Ki-Young
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2018, 256
  • [29] Modular Entry to Functionalized Tetrahydrobenzo[b]azepines via the Palladium/Norbornene Cooperative Catalysis Enabled by a C7-Modified Norbornene
    Liu, Xin
    Wang, Jianchun
    Dong, Guangbin
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2021, 143 (26) : 9991 - 10004
  • [30] Deoxygenative ortho-benzylation of aryl iodides with benzyl alcohol via palladium/norbornene cooperative catalysis
    Ling, Shaowen
    Zheng, Shuaichen
    Xu, Baolong
    Liu, Hui
    Li, Xinjin
    Sun, Feng-Gang
    ORGANIC CHEMISTRY FRONTIERS, 2025,
12345