A facile synthesis of benzo[b][1,4]thiazepine derivatives by palladium acetate catalyzed reaction

被引：13
|
作者：
Kaishap, Partha Pratim [1 ]
Shekarrao, Kommuri [1 ]
Saikia, Pallabi [1 ]
Gogoi, Sanjib [1 ]
Boruah, Romesh C. [1 ]
机构：
[1] North East Inst Sci & Technol, Div Med Chem, Jorhat 785006, Assam, India
来源：
TETRAHEDRON LETTERS | 2014年 / 55卷 / 11期
关键词：
Benzo[b][1,4]thiazepine; Steroid; Palladium acetate; beta-Bromovinyl aldehyde; 2-Aminothiophenol; 1,3-DIPOLAR CYCLOADDITION; 1,5-BENZOTHIAZEPINES; QUINOLINES; PYRIDINE; SOLVENT;
D O I：
10.1016/j.tetlet.2014.01.153
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The preparation of steroid/nonsteroid fused benzo[b][1,4]thiazepines and 2-arylsubstituted benzo[b][1,4] thiazepines is described from Pd(OAc)(2) catalyzed reaction of steroidal/nonsteroidal beta-halovinyl aldehydes and 2-aminothiophenols in DMF under heating condition. (c) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码：1927 / 1930
页数：4
相关论文
共 50 条
  • [21] Propenethioamides in the synthesis of heterocyclic systems. Synthesis of pyrrole and 1,4-thiazepine derivatives
    Cocco, MT
    Congiu, C
    Onnis, V
    JOURNAL OF HETEROCYCLIC CHEMISTRY, 1995, 32 (06) : 1679 - 1682
  • [22] Synthesis of Benzo[1,4]heterocycles using Palladium Catalyzed Heck Reaction to Vinylogous Carbonates/Carbamates: Unexpected Formation of Indoles via Carbopalladation Intercepted by Nucleopalladation
    Gharpure, Santosh J.
    Anuradha, Dandela
    ORGANIC LETTERS, 2017, 19 (22) : 6136 - 6139
  • [23] THE REACTION OF ALKENYLBORANES WITH PALLADIUM ACETATE - STEREOSELECTIVE SYNTHESIS OF OLEFINIC DERIVATIVES
    YATAGAI, H
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1980, 53 (06) : 1670 - 1676
  • [24] Discovery of novel benzo[b][1,4]oxazine derivatives as ferroptosis inhibitors
    Wan, Bi-Wen
    Liu, Wei
    Xiao, Yijie
    Lv, Lijie
    Li, Xuan
    Lin, Fang
    Zhao, Yahui
    He, Yi
    Nie, Shenyou
    Yang, Xiaoyu
    Yuan, Hai-Xin
    BIOORGANIC CHEMISTRY, 2025, 156
  • [25] Facile Synthesis of Benzoxazinone Derivatives via Palladium Catalyzed Intramolecular Amination
    Zhou, Panpan
    Guan, Mingyu
    Zhang, Jingyu
    Xu, Fan
    Zhao, Yingsheng
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2017, 37 (08) : 2028 - 2033
  • [26] Synthesis and Anticancer Activity Evaluation of Benzo[f][1,4] oxazepinone Derivatives
    Li, Fengqiong
    Mu, Minjie
    Yang, Na
    Zhong, Ling
    Hu, Rong
    Li, Jinqi
    Bai, Lan
    Shi, Jianyou
    Zhang, Mei
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2016, 36 (06) : 1419 - 1425
  • [27] Efficient synthesis of novel benzo-[e]-[1,4]-diazepine derivatives
    Messeri, T
    Pentassuglia, G
    Di Fabio, R
    TETRAHEDRON LETTERS, 2001, 42 (18) : 3227 - 3230
  • [28] Synthesis of 1,4:3,6-Dianhydrohexitols Diesters from the Palladium-Catalyzed Hydroesterification Reaction
    Pruvost, Romain
    Boulanger, Jerome
    Leger, Bastien
    Ponchel, Anne
    Monflier, Eric
    Ibert, Mathias
    Mortreux, Andre
    Chenal, Thomas
    Sauthier, Mathieu
    CHEMSUSCHEM, 2014, 7 (11) : 3157 - 3163
  • [29] A facile and environmentally benign synthesis of 2H-benzo[b] [1,4] oxazines of potential biological importance
    Zhimomi, Betokali K.
    Imchen, Putusenla
    Phom, Manthae
    Achumi, Phitovili
    Tumtin, Shokip
    Swu, Toka
    Phucho, Tovishe
    ARKIVOC, 2024,
  • [30] AN ABNORMAL REFORMATSKY REACTION - SYNTHESIS OF BENZO(B)THIOPHENE AND BENZO(B)SELENOPHENE DERIVATIVES
    RUWET, A
    RENSON, M
    BULLETIN DES SOCIETES CHIMIQUES BELGES, 1970, 79 (1-2): : 75 - &
12345