A facile synthesis of benzo[b][1,4]thiazepine derivatives by palladium acetate catalyzed reaction

被引：13
|
作者：
Kaishap, Partha Pratim [1 ]
Shekarrao, Kommuri [1 ]
Saikia, Pallabi [1 ]
Gogoi, Sanjib [1 ]
Boruah, Romesh C. [1 ]
机构：
[1] North East Inst Sci & Technol, Div Med Chem, Jorhat 785006, Assam, India
来源：
TETRAHEDRON LETTERS | 2014年 / 55卷 / 11期
关键词：
Benzo[b][1,4]thiazepine; Steroid; Palladium acetate; beta-Bromovinyl aldehyde; 2-Aminothiophenol; 1,3-DIPOLAR CYCLOADDITION; 1,5-BENZOTHIAZEPINES; QUINOLINES; PYRIDINE; SOLVENT;
D O I：
10.1016/j.tetlet.2014.01.153
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The preparation of steroid/nonsteroid fused benzo[b][1,4]thiazepines and 2-arylsubstituted benzo[b][1,4] thiazepines is described from Pd(OAc)(2) catalyzed reaction of steroidal/nonsteroidal beta-halovinyl aldehydes and 2-aminothiophenols in DMF under heating condition. (c) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码：1927 / 1930
页数：4
相关论文
共 50 条
  • [1] Progress in Synthesis and Application of Benzo[b][1,4]diazepine Derivatives
    Yin, Liuyan
    Wang, Lanzhi
    Li, Xiaoqing
    An, Yingshuang
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2016, 36 (04) : 711 - 723
  • [2] Synthesis and Crystal Structure of Novel Derivatives of 1,5-Benzo[b]thiazepine
    Ye, Jiawei
    Yang, Chun
    Yang, Debao
    Liu, Fangming
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2009, 29 (03) : 414 - 419
  • [3] Synthesis of substituted benzo[b][1,4]oxazepine derivatives by the reaction of 2-aminophenols with alkynones
    Oshimoto, Kohei
    Zhou, Biao
    Tsuji, Hiroaki
    Kawatsura, Motoi
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2020, 18 (03) : 415 - 419
  • [4] Samarium diiodide catalyzed synthesis of 2,3-dihydro-1H-benzo[b][1,4]-diazepine derivatives
    Luo, YQ
    Xu, F
    Han, XY
    Shen, Q
    CHINESE JOURNAL OF CHEMISTRY, 2005, 23 (10) : 1417 - 1420
  • [5] A Domino Reaction for the Selective Synthesis of Functionalized Benzo[b][1,4]diazepines
    Sun, Yuewei
    Zhou, Laiyun
    Wang, Lanzhi
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2019, 39 (12) : 3516 - 3523
  • [6] A FACILE SYNTHESIS OF BENZO[B]THIOPHENE DERIVATIVES
    WATANABE, M
    DATE, M
    KAWANISHI, K
    AKIYOSHI, R
    FURUKAWA, S
    JOURNAL OF HETEROCYCLIC CHEMISTRY, 1991, 28 (01) : 173 - 176
  • [7] Palladium-catalyzed tandem reaction of o-aminophenols, bromoalkynes and isocyanides to give 4-amine-benzo[b][1,4] oxazepines
    Liu, Bifu
    Li, Yibiao
    Yin, Meizhou
    Wu, Wanqing
    Jiang, Huanfeng
    CHEMICAL COMMUNICATIONS, 2012, 48 (93) : 11446 - 11448
  • [8] NEW SYNTHESIS OF DIBENZO[B,F-1,4]OXAZEPINE DIBENZO[B,F-1,4]THIAZEPINE + DIBENZO[B,E-1,4]DIAZEPINE DERIVATIVES
    NAGARAJAN, K
    KULKARNI, CL
    VENKATES.A
    INDIAN JOURNAL OF CHEMISTRY, 1968, 6 (04): : 225 - +
  • [9] Metal-Catalyzed Cyclization: Synthesis of (Benzo)morpholines and (Benzo)[1,4]dihydrooxazines
    Aubineau, Thomas
    Cossy, Janine
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2019, 2019 (46) : 7513 - 7531
  • [10] Palladium(0)-catalyzed synthesis of 2-vinyl-2,3-dihydro-benzo[1,4]dioxins
    Massacret, M
    Lhoste, P
    Lakhmiri, R
    Parella, T
    Sinou, D
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 1999, 1999 (10) : 2665 - 2673
12345