A Novel Fluorescent Fluoride Chemosensor Based on Unmodified Poly(amidoamine) Dendrimer

被引:7
|
作者
Yamaji, Daisuke [1 ]
Takaguchi, Yutaka [1 ]
机构
[1] Okayama Univ, Grad Sch Environm Sci, Okayama 7008530, Japan
关键词
Dendrimer; Poly(amidoamine); Chemosensor; Fluoride Ion; Fluorescence; PAMAM; IONS; DEPENDENCE; EMISSION; PROTONS; COMPLEX; SENSOR;
D O I
10.1295/polymj.PJ2008240
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The methanol solution of G4.5 COONa-terminated PAMAM dendrimer displayed strong blue luminescence (lambda(max) = 445 nm) under UV irradiation at 370 nm and fluorescence intensity increased with fluoride ions. On the other hand, the remarkable changes of fluorescence spectra of the dendrimer solutions were not observed in the presence of other halogen anions (Cl-, Br-, and I-). This result suggested that the PAMAM dendrimer is useful as fluoride ion selective sensor in methanol.
引用
收藏
页码:293 / 296
页数:4
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