Stereoselective syntheses of (E)-1-boryl-3-(silyl)propenes via ruthenium-catalyzed cross-metathesis and cross-coupling reactions

被引：19

作者：

Jankowska, Magdalena

Pietraszuk, Cezary

Marciniec, Bogdan ^{[1
]}

Zaidlewicz, Marek

机构：

[1] Adam Mickiewicz Univ, Fac Chem, PL-60780 Poznan, Poland

[2] Nicholas Copernicus Univ, Dept Chem, PL-87100 Torun, Poland

来源：

SYNLETT | 2006年 / 11期

关键词：

silylative coupling; cross-metathesis; organic synthesis; organosilicon compounds; organoboron compounds;

D O I：

10.1055/s-2006-944212

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A general and mostly highly stereoselective method for effective synthesis of 1-boryl-3-(silyl)propenes via one-step catalytic processes, i.e. silylative coupling of vinylsilanes with allyl boronates, borylative coupling of vinyl boronates with allylsilanes catalysed by [RuHCl(CO)(PCy3)(2)] and cross-metathesis of respective derivatives in the presence of Grubbs catalysts, is described.

引用

页码：1695 / 1698

页数：4

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