Stereoselective syntheses of (E)-1-boryl-3-(silyl)propenes via ruthenium-catalyzed cross-metathesis and cross-coupling reactions

被引：19
|
作者：
Jankowska, Magdalena
Pietraszuk, Cezary
Marciniec, Bogdan [1 ]
Zaidlewicz, Marek
机构：
[1] Adam Mickiewicz Univ, Fac Chem, PL-60780 Poznan, Poland
[2] Nicholas Copernicus Univ, Dept Chem, PL-87100 Torun, Poland
来源：
SYNLETT | 2006年 / 11期
关键词：
silylative coupling; cross-metathesis; organic synthesis; organosilicon compounds; organoboron compounds;
D O I：
10.1055/s-2006-944212
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A general and mostly highly stereoselective method for effective synthesis of 1-boryl-3-(silyl)propenes via one-step catalytic processes, i.e. silylative coupling of vinylsilanes with allyl boronates, borylative coupling of vinyl boronates with allylsilanes catalysed by [RuHCl(CO)(PCy3)(2)] and cross-metathesis of respective derivatives in the presence of Grubbs catalysts, is described.
引用
收藏
页码：1695 / 1698
页数：4
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