Crystal chemistry and thermal expansion of Cd0.5Zr2(PO4)(3) and Cd0.25Sr0.25Zr2(PO4)(3) ceramics

被引：38

作者：

Brochu, R ^{[1
]}

ElYacoubi, M ^{[1
]}

Louer, M ^{[1
]}

Serghini, A ^{[1
]}

Alami, M ^{[1
]}

Louer, D ^{[1
]}

机构：

[1] FAC SCI RABAT,DEPT CHIM,CHIM SOLIDE LAB,RABAT,MOROCCO

来源：

MATERIALS RESEARCH BULLETIN | 1997年 / 32卷 / 01期

关键词：

inorganic compounds; ceramics; X-ray diffraction; microstructure; thermal expansion;

D O I：

10.1016/S0025-5408(96)00162-6

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Cd0.5Zr2(PO4)(3) (CdZP) and the partially substituted phase Cd0.25Sr0.25Zr2(PO4)(3), prepared by the sol-gel route, belong to the NZP family. The structure of CdZP (S.G.R (3) over bar) has been established by the Rietveld method. The thermal behavior of CdZP, investigated by X-ray powder diffraction, is anisotropic, i.e., the structure expands along c axis and contracts along a axis. Dilatometric measurements and SEM micrographs of ceramics, sintered with 5% ZnO, show that CdSrZP presents the advantage to decrease microcracking, and then anisotropy,occurring during the heating cycle. The thermal expansion coefficient a(bulk) of the ceramic CdSrZP is very small (0.6 x 10(-6)degrees C-1).

引用

页码：15 / 23

页数：9

共 50 条

[31] Synthesis and crystal chemical characteristics of the structure of M0.5Zr2(PO4)3 phosphates
Pet'kov, VI
Kurazhkovskaya, VS
Orlova, AI
Spiridonova, ML
CRYSTALLOGRAPHY REPORTS, 2002, 47 (05) : 736 - 743
[32] Synthesis and crystal chemical characteristics of the structure of M0.5Zr2(PO4)3 phosphates
V. I. Pet’kov
V. S. Kurazhkovskaya
A. I. Orlova
M. L. Spiridonova
Crystallography Reports, 2002, 47 : 736 - 743
[33] TERNARY PHOSPHATES IN THE SYSTEMS CA3(PO4)2-NA3ND(PO4)2, CA3(PO4)2-NA3U(PO4)2, CA3(PO4)2-NA3ER(PO4)2
LAZORYAK, BI
IVANOV, LN
STRUNENKOVA, TV
GOLUBEV, VN
VITING, BN
INORGANIC MATERIALS, 1990, 26 (02) : 283 - 286
[34] Synthesis, Structure, and Thermal Expansion of BiCr2(PO4)3, SbCr2(PO4)3, and Bi1-xSb.Cr2(PO4)3 Solid Solution
Pet'kov, V. I.
Lavrenov, D. A.
Asabina, E. A.
RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2023, 93 (03) : 586 - 592
[35] Sr3Cu3(PO4)4, Pb3Cu3(PO4)4, BaCu2(PO4)2•H2O, and Ba2Cu(PO4)2•H2O:: Crystal structures and topological relationships
Effenberger, H
JOURNAL OF SOLID STATE CHEMISTRY, 1999, 142 (01) : 6 - 13
[36] Pressure dependence of negative thermal expansion in Zr2(WO4)(PO4)2
Cetinkol, Mehmet
Wilkinson, Angus P.
SOLID STATE COMMUNICATIONS, 2009, 149 (11-12) : 421 - 424
[37] Temperature dependences of phase composition, densification, and thermal/chemical stability of Sr0.5Zr2(PO4)3-Nd0.5Sm0.5PO4 composite ceramics for nuclear waste form
Liu, Die
Wang, Junxia
Wang, Jin
Liu, Kunqi
Wen, Jianwu
Xu, Jiaqi
Jiang, Peng
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2024, 44 (16)
[38] A robust hydrothermal synthesis method of NH4Zr2(PO4)3, a precursor for HZr2(PO4)3 proton conductor
Paiva, Lara F. Almeida
Durana, E.
Holz, Laura I. V.
Gratca, Manuel P. F.
Fagg, Duncan P.
CERAMICS INTERNATIONAL, 2024, 50 (17) : 29603 - 29612
[39] Structure and thermal expansion of KGe2(PO4)(3)
Brochu, R
Louer, M
Alami, M
Alqaraoui, M
Louer, D
MATERIALS RESEARCH BULLETIN, 1997, 32 (01) : 113 - 122
[40] Synthesis and Study of the Phosphate Cs2Mn0.5Zr1.5(PO4)3
Zaripov, A. R.
Orlova, V. A.
Pet'kov, V. I.
Slyunchev, O. M.
Galuzin, D. D.
Rovnyi, S. I.
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2009, 54 (01) : 45 - 51

← 1 2 3 4 5 →