POBOP pincer complexes of nickel(II): Synthesis and B-H activation of the carborane ligand upon oxidation with iodine

被引：20
|
作者：
Eleazer, Bennett J. [1 ]
Smith, Mark D. [1 ]
Peryshkov, Dmitry V. [1 ]
机构：
[1] Univ South Carolina, Dept Chem & Biochem, 631 Sumter St, Columbia, SC 29208 USA
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2017年 / 829卷
关键词：
Carboranes; Pincer complexes; Nickel; DIPHOSPHINITO POCOP COMPLEXES; METAL; CATALYSIS; BORON; BOND; DERIVATIVES; SUBSTITUENTS; BACKBONE; RUTHENIUM; RHODIUM;
D O I：
10.1016/j.jorganchem.2016.10.040
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The (POBOP)NiCl pincer complex (POBOP = 1,7-OP(i-Pr)(2)-m-carboranyl) was synthesized by the selective B-H activation of the chelating carboranyl ligand and structurally and spectroscopically characterized. The reaction of (POBOP)NiCl and 1 equiv. of I-2 at room temperature led to the selective iodination of the vicinal B-H bond in the complex. The reaction of (POBOP)NiCl and 7 equiv. of I-2 at room temperature led to further iodination of the ligand and dissociation of the metal from the complex. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码：42 / 47
页数：6
相关论文
共 50 条
  • [41] Sterically encumbered dianionic dicarboranyl pincer ligand (C5H3N)(C2B10H11)2 and its CNC Nickel(II) complex
    Islam, Mohammad Jahirul
    Smith, Mark D.
    Peryshkov, Dmitry V.
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2018, 867 : 208 - 213
  • [42] Cobalt-Mediated Selective B-H Activation and Formation of a Co-B Bond in the Reaction of the 16-Electron CpCo Half-Sandwich Complex Containing an o-Carborane-1,2-dithiolate Ligand with Ethyl Diazoacetate
    Liu, Guifeng
    Hu, Jiurong
    Wen, Jialin
    Dai, Huimin
    Li, Yizhi
    Yan, Hong
    INORGANIC CHEMISTRY, 2011, 50 (09) : 4187 - 4194
  • [43] Synthesis, structure, magnetic properties and biological activity of supramolecular copper(II) and nickel(II) complexes with a Schiff base ligand derived from vitamin B6
    Mukherjee, Tirtha
    Pessoa, Joao Costa
    Kumar, Amit
    Sarkar, Asit R.
    DALTON TRANSACTIONS, 2013, 42 (07) : 2594 - 2607
  • [44] Synthesis of Quinoline-Based NNN-Pincer Nickel(II) Complexes: A Robust and Improved Catalyst System for C-H Bond Alkylation of Azoles with Alkyl Halides
    Patel, Ulhas N.
    Pandey, Dilip K.
    Gonnade, Rajesh G.
    Punji, Benudhar
    ORGANOMETALLICS, 2016, 35 (11) : 1785 - 1793
  • [45] Electrocatalytic hydrogen production and hydrogen oxidation using tetradentate nickel (II) and zinc (II) complexes with P2S2 ligand framework: Synthesis, characterization and mechanistic insights
    Jain, Rahul
    Haddad, Andrew
    Mashuta, Mark
    Buchanan, Robert
    Grapperhaus, Craig
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 254
  • [46] Synthesis, Characterization and DFT calculations of Novel Mononuclear Nickel (II), Cobalt (II) and Iron (II) Complexes derived from 2-(1H-benzimidazol-2-yl)- phenol Ligand
    Haghverdi, Marzieh
    Tadjarodi, Azadeh
    20TH INTERNATIONAL ELECTRONIC CONFERENCE ON SYNTHETIC ORGANIC CHEMISTRY (ECSOC), 2016,
  • [47] Synthesis of a labile sulfur-centred ligand, [S(H)C(PPh2S)2]-: structural diversity in lithium(I), zinc(II) and nickel(II) complexes
    Thirumoorthi, Ramalingam
    Chivers, Tristram
    Haggman, Susanna
    Mansikkamaki, Akseli
    Morgan, Ian S.
    Tuononen, Heikki M.
    Lahtinen, Manu
    Konu, Jari
    DALTON TRANSACTIONS, 2016, 45 (32) : 12691 - 12701
  • [48] Facile synthesis of Pd(ii) and Ni(ii) pincer carbene complexes by the double C-H bond activation of a new hexahydropyrimidine-based bis(phosphine): catalysis of C-N couplings
    Subramaniyan, Vasudevan
    Dutta, Bidisa
    Govindaraj, Anbarasu
    Mani, Ganesan
    DALTON TRANSACTIONS, 2019, 48 (21) : 7203 - 7210
  • [49] Bimetallic Mixed-Ligand Cobalt(II), Nickel(II), and Copper(II) Complexes [MHg(C6H6N2O)2(SCN)4]: Synthesis and Crystal Structure
    Cherkasova, T. G.
    Pervukhina, N., V
    Kurateva, N., V
    Barantsev, D. A.
    Tatarinova, E. S.
    Cherkasova, E., V
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2019, 64 (04) : 459 - 464
  • [50] Bimetallic Mixed-Ligand Cobalt(II), Nickel(II), and Copper(II) Complexes [MHg(C6H6N2O)2(SCN)4]: Synthesis and Crystal Structure
    T. G. Cherkasova
    N. V. Pervukhina
    N. V. Kurateva
    D. A. Barantsev
    E. S. Tatarinova
    E. V. Cherkasova
    Russian Journal of Inorganic Chemistry, 2019, 64 : 459 - 464
12345