POBOP pincer complexes of nickel(II): Synthesis and B-H activation of the carborane ligand upon oxidation with iodine

被引：20

作者：

Eleazer, Bennett J. ^{[1
]}

Smith, Mark D. ^{[1
]}

Peryshkov, Dmitry V. ^{[1
]}

机构：

[1] Univ South Carolina, Dept Chem & Biochem, 631 Sumter St, Columbia, SC 29208 USA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2017年 / 829卷

关键词：

Carboranes; Pincer complexes; Nickel; DIPHOSPHINITO POCOP COMPLEXES; METAL; CATALYSIS; BORON; BOND; DERIVATIVES; SUBSTITUENTS; BACKBONE; RUTHENIUM; RHODIUM;

D O I：

10.1016/j.jorganchem.2016.10.040

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The (POBOP)NiCl pincer complex (POBOP = 1,7-OP(i-Pr)(2)-m-carboranyl) was synthesized by the selective B-H activation of the chelating carboranyl ligand and structurally and spectroscopically characterized. The reaction of (POBOP)NiCl and 1 equiv. of I-2 at room temperature led to the selective iodination of the vicinal B-H bond in the complex. The reaction of (POBOP)NiCl and 7 equiv. of I-2 at room temperature led to further iodination of the ligand and dissociation of the metal from the complex. (C) 2016 Elsevier B.V. All rights reserved.

引用

页码：42 / 47

页数：6

共 50 条

[31] Manganese(II), Nickel(II), and Palladium(II) Complexes of a Terpyridine-Like Ligand Containing a Sulfur Linkage, and an Analogous NCN Pincer Palladium(II) Complex: Synthesis, Characterization, and Pd-Catalyzed Reactions
Hirotsu, Masakazu
Tsukahara, Yuhei
Kinoshita, Isamu
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2010, 83 (09) : 1058 - 1066
[32] Synthesis and structure of rhodium complexes with monoanionic carborane ligand [9-SMe2-7,8-C2B9H10]-
Kudinov, AR
Perekalin, DS
Petrovskii, PV
Lyssenko, KA
Grintselev-Knyazev, GV
Starikova, ZA
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2002, 657 (1-2) : 115 - 122
[33] Unsymmetrical Chiral PCN Pincer Palladium(II) and Nickel(II) Complexes with Aryl-Based Aminophosphine-Imidazoline Ligands: Synthesis via Aryl C-H Activation and Asymmetric Addition of Diarylphosphines to Enones
Yang, Ming-Jun
Liu, Yan-Jing
Gong, Jun-Fang
Song, Mao-Ping
ORGANOMETALLICS, 2011, 30 (14) : 3793 - 3803
[34] Cooperative B-H Activation: Ligand Diversity in Groups 6 and 8 Transition Metal κ2-N,E-Chelated Complexes (E = S or Se)
Saha, Suvam
Mohapatra, Stutee
Kumar, Manish
Yadav, Dibya
Ghosh, Sundargopal
INORGANIC CHEMISTRY, 2025, 64 (06) : 2618 - 2629
[35] Thiosemicarbazone ligand, nickel(II) and ruthenium(II) complexes based on vitamin B6 vitamer: The synthesis, different coordination behaviors and antioxidant activities
Bal-Demirci, Tulay
Guveli, Sukriye
Yesilyurt, Saffet
Ozdemir, Namik
Ulkuseven, Bahri
INORGANICA CHIMICA ACTA, 2020, 502
[36] Zwitterionic half-sandwich Rh and Ir complexes containing a diphosphine nido-carborane ligand: synthesis, structure transformation and application in H2 activation
Yao, Zi-Jian
Huo, Xian-Kuan
Jin, Guo-Xin
CHEMICAL COMMUNICATIONS, 2012, 48 (53) : 6714 - 6716
[37] Pd(II)-catalyzed synthesis of bifunctionalized carboranes via cage B-H activation of 1-CH2NH2-o-carboranes
Zhang, Xiaolei
Yan, Hong
CHEMICAL SCIENCE, 2018, 9 (16) : 3964 - 3969
[38] B-C bond cleavage of BArF anion upon oxidation of rhodium(I) with AgBArF.: Phosphinite rhodium(I), rhodium(II), and rhodium(III) pincer complexes
Salem, Hiyam
Shimon, Linda J. W.
Leitus, Gregory
Weiner, Lev
Milstein, David
ORGANOMETALLICS, 2008, 27 (10) : 2293 - 2299
[39] Synthesis and characterization of nickel(II), cobalt(II) manganese(II), copper(II), iron(III) and chromium(III) complexes of unsymmetrical salen-type ligand and their application as catalysts for the oxidation of styrene
Maldhure, Atish K.
Aswar, Anand S.
JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 2009, 86 (07) : 697 - 702
[40] Cooperative B-H activation by Cp* based κ2-N,S-chelated Ru(II) and Mo(II) complexes (Cp* = η5-C5Me5)
Saha, Suvam
Haridas, Anagha
Assanar, Faneesha
Bansal, Charu
Antharjanam, P. K. Sudhadevi
Ghosh, Sundargopal
DALTON TRANSACTIONS, 2022, 51 (12) : 4806 - 4813

← 1 2 3 4 5 →