Influence of temperature upon properties of tailor-made PEBAX® MU 1657 nanocomposite membranes for post-combustion CO2 capture

被引：39

作者：

Rahman, Md. Mushfequr ^{[1
]}

Shishatskiy, Sergey ^{[1
]}

Abetz, Clarissa ^{[1
]}

Georgopanos, Prokopios ^{[1
]}

Neumann, Silvio ^{[1
]}

Khan, Muntazim Munir ^{[1
]}

Filiz, Volkan ^{[1
]}

Abetz, Volker ^{[1
,2
]}

机构：

[1] Helmholtz Zentrum Geesthacht, Polymer Res Inst, D-21502 Geesthacht, Germany

[2] Univ Hamburg, Inst Phys Chem, D-20146 Hamburg, Germany

来源：

JOURNAL OF MEMBRANE SCIENCE | 2014年 / 469卷

关键词：

PEBAX (R); POSS; Nanocomposite; Gas separation membrane; Mixed-matrix-membrane; GAS-TRANSPORT PROPERTIES; PEG FUNCTIONALIZED POSS; PERMEATION; BEHAVIOR;

D O I：

10.1016/j.memsci.2014.06.048

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Tailor-made block copolymer nanocomposite membranes are prepared by incorporation of 40 wt% methoxy poly(ethylene glycol) (PEG) functionalized polyoctahedral oligomeric silsesquioxanes (POSS) nanoparticles in commercial thermoplastic elastomer multiblock copolymer PEBAX (R) MH 1657. Atomic force microscopy was used to find out the location of the nanoparticles in the block copolymer matrix. Separation of CO2 from N-2 and H-2 is studied by measurements of single gas transport properties of nanocomposite materials using the time-lag method in the temperature range 30-70 degrees C. PEG functionalized POSS nanoparticles increase the CO2 permeability of the nanocomposite membranes without loss of CO2/N-2 and CO2/H-2 selectivity. Thermal properties of the nanocomposite membranes are studied by differential scanning calorimetry (DSC) to assess the stability of the nanocomposite membranes upon melting of polyether and polyamide blocks. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：344 / 354

页数：11

共 50 条

[41] Evaluation of carbon nanoscroll materials for post-combustion CO2 capture
Daff, Thomas D.
Collins, Sean P.
Dureckova, Hana
Perim, Eric
Skaf, Munir S.
Galvao, Douglas S.
Woo, Tom K.
CARBON, 2016, 101 : 218 - 225
[42] Comparison of solvents for post-combustion capture of CO2 by chemical absorption
Kothandaraman, Anusha
Nord, Lars
Bolland, Olav
Herzog, Howard J.
McRae, Gregory J.
GREENHOUSE GAS CONTROL TECHNOLOGIES 9, 2009, 1 (01): : 1373 - 1380
[43] Benchmarking of the pre/post-combustion chemical absorption for the CO2 capture
Dinca, Cristian
Slavu, Nela
Badea, Adrian
JOURNAL OF THE ENERGY INSTITUTE, 2018, 91 (03) : 445 - 456
[44] Templated polymeric materials as adsorbents for the post-combustion capture of CO2
Drage, Trevor C.
Pevida, Covadonga
Snape, Colin
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2007, 233
[45] Phase change ionic liquids for post-combustion CO2 capture
Brennecke, Joan
Seo, Samuel
Simoni, Lluke
Stadtherr, Mark
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2015, 249
[46] Deactivation causes of dry sorbents for post-combustion CO2 capture
Cho, Min Sun
Chae, Ho Jin
Lee, Soo Chool
Jo, Seong Bin
Kim, Tae young
Lee, Chul Ho
Baek, Jeom-In
Kim, Jae Chang
KOREAN CHEMICAL ENGINEERING RESEARCH, 2019, 57 (02): : 253 - 258
[47] Assessment of the technology readiness of post-combustion CO2 capture technologies
Freeman, Brice C.
Bhown, Abhoyjit S.
10TH INTERNATIONAL CONFERENCE ON GREENHOUSE GAS CONTROL TECHNOLOGIES, 2011, 4 : 1791 - 1796
[48] Exergy Recuperative CO2 Gas Separation in Post-Combustion Capture
Kishimoto, Akira
Kansha, Yasuki
Fushimi, Chihiro
Tsutsumi, Atsushi
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2011, 50 (17) : 10128 - 10135
[49] Recyclability of Encapsulated Ionic Liquids for Post-Combustion CO2 Capture
Song, Tangqiumei
Bonilla, Gabriela M. Avelar
Morales-Collazo, Oscar
Lubben, Michael J.
Brennecke, Joan F.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2019, 58 (12) : 4997 - 5007
[50] Evaluation of a molecular basket sorbent for post-combustion CO2 capture
Coleman, Luke
Wang, Xiaoxing
Ma, Xiaoliang
Nelson, Thomas
Lail, Marty
Gupta, Raghubir
Song, Chunshan
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2011, 241

← 1 2 3 4 5 →