Synthesis, Structural, Magnetic and Electrical Characterization of Poly(o-phenylenediamine)/CoFe2O4 Nanocomposites

被引:4
|
作者
Kannapiran, Nagarajan [1 ]
Muthusamy, Athianna [1 ]
Anand, Siddeswaran [1 ]
Jayaprakash, Rajan [2 ]
机构
[1] Sri Ramakrishna Mission Vidyalaya Coll Arts & Sci, PG & Res Dept Chem, Coimbatore 641020, Tamil Nadu, India
[2] Sri Ramakrishna Mission Vidyalaya Coll Arts & Sci, Dept Phys, Coimbatore 641020, Tamil Nadu, India
关键词
PoPD; CoFe2O4; TEM; Dielectric constant; DIELECTRIC-PROPERTIES; FERRITE NANOPARTICLES;
D O I
10.1007/s10948-017-4343-7
中图分类号
O59 [应用物理学];
学科分类号
摘要
CoFe2O4 nanoparticles were prepared by an auto-combustion method, and poly(o-phenylenediamine) (PoPD)/CoFe2O4 nanocomposites containing different ratios CoFe2O4 (10, 20 and 30%) were synthesized by an in situ chemical oxidative polymerization method. Dielectric constant and loss of PoPD/CoFe2O4 nanocomposites were varied based on the dopant concentration. The crystalline sizes of the CoFe2O4 nanoparticles and PoPD/CoFe2O4 nanocomposites were calculated using XRD pattern, and it is also confirmed nanoparticles embedded in the PoPD matrix. The hysteresis loops of CoFe2O4 and nanocomposites show a ferromagnetic behaviour, and saturation magnetization of PoPD/CoFe2O4 nanocomposites increases with an increase in concentration of CoFe2O4 nanoparticles. TEM micrograph of PoPD/CoFe2O4 nanocomposites demonstrated CoFe2O4 nanoparticles deposited on the surface of PoPD matrix.
引用
收藏
页码:1489 / 1497
页数:9
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