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Green Synthesized Fluorescent Carbon Dots from Momordica charantia for Selective and Sensitive Detection of Pd2+ and Fe3+
被引:24
|作者:
Dong, Yan
[1
]
Zhang, Yudong
[1
]
Zhi, Shumin
[1
]
Yang, Xueyun
[1
]
Yao, Cheng
[1
]
机构:
[1] Nanjing Tech Univ, Grad Sch Chem Mol Engn, Dept Chem, Nanjing 211816, Peoples R China
来源:
关键词:
Fluorescent carbon dots;
Fe3+;
Momordica charantia;
Pd2+;
Static quenching effect;
QUANTUM DOTS;
RED-EMISSION;
PALLADIUM;
PROBE;
IRON;
NANODOTS;
SENSOR;
TOXICITY;
ACID;
D O I:
10.1002/slct.202004060
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
A facile and rapid fluorescent sensing system for palladium ion (Pd2+) and iron ion (Fe3+) has been established based on carbon dots (CDs) using fresh Momordica charantia as the sole precursor via a one-step hydrothermal treatment. The added Pd2+ and Fe3+ lead to the fluorescence quenching of CDs due to the static quenching effect (SQE). Such fluorescence response can be quenched by Pd2+ and Fe3+ in the linear ranges of 0-325 mu M and 0-150 mu M. Meanwhile, this sensing system exhibits good selectivity and sensitivity toward Pd2+ and Fe3+ over other analytes with low detection limits of 0.348 mu M and 0.175 mu M, respectively. Furthermore, the proposed sensing system has been successfully used for Pd2+ and Fe3+ in tap and environmental water and the recoveries range from 96.25 % to 107.3 %. The results mentioned above demonstrate its great promise as a practical platform for Pd2+ and Fe3+ sensing in aqueous media.
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页码:123 / 130
页数:8
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