Green Synthesized Fluorescent Carbon Dots from Momordica charantia for Selective and Sensitive Detection of Pd2+ and Fe3+

被引:24
|
作者
Dong, Yan [1 ]
Zhang, Yudong [1 ]
Zhi, Shumin [1 ]
Yang, Xueyun [1 ]
Yao, Cheng [1 ]
机构
[1] Nanjing Tech Univ, Grad Sch Chem Mol Engn, Dept Chem, Nanjing 211816, Peoples R China
来源
CHEMISTRYSELECT | 2021年 / 6卷 / 01期
关键词
Fluorescent carbon dots; Fe3+; Momordica charantia; Pd2+; Static quenching effect; QUANTUM DOTS; RED-EMISSION; PALLADIUM; PROBE; IRON; NANODOTS; SENSOR; TOXICITY; ACID;
D O I
10.1002/slct.202004060
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A facile and rapid fluorescent sensing system for palladium ion (Pd2+) and iron ion (Fe3+) has been established based on carbon dots (CDs) using fresh Momordica charantia as the sole precursor via a one-step hydrothermal treatment. The added Pd2+ and Fe3+ lead to the fluorescence quenching of CDs due to the static quenching effect (SQE). Such fluorescence response can be quenched by Pd2+ and Fe3+ in the linear ranges of 0-325 mu M and 0-150 mu M. Meanwhile, this sensing system exhibits good selectivity and sensitivity toward Pd2+ and Fe3+ over other analytes with low detection limits of 0.348 mu M and 0.175 mu M, respectively. Furthermore, the proposed sensing system has been successfully used for Pd2+ and Fe3+ in tap and environmental water and the recoveries range from 96.25 % to 107.3 %. The results mentioned above demonstrate its great promise as a practical platform for Pd2+ and Fe3+ sensing in aqueous media.
引用
收藏
页码:123 / 130
页数:8
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