The formation, reactivity and interconversion of novel η1- and η3-triazacyclononane complexes of rhodium(I) and rhodium(III)

被引：10

作者：

Gott, AL ^{[1
]}

McGowan, PC ^{[1
]}

Temple, CN ^{[1
]}

机构：

[1] Univ Leeds, Dept Chem, Leeds LS2 9JT, W Yorkshire, England

来源：

DALTON TRANSACTIONS | 2004年 / 12期

关键词：

D O I：

10.1039/b401877j

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We have successfully synthesised and characterised a number of. eta(1)- and eta(3)-triazacyclononane Rh-I and Rh-III derivatives. By using different reaction conditions, we have been able to convert one of the eta(1)-triazacyclononane complexes to an eta(3)-derivative. Also, we have observed a rare example of an addition of an organic fragment to a metal bound ligand to form a quaternary carbon centre.

引用

页码：1841 / 1845

页数：5

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