The formation, reactivity and interconversion of novel η1- and η3-triazacyclononane complexes of rhodium(I) and rhodium(III)

被引：10

作者：

Gott, AL ^{[1
]}

McGowan, PC ^{[1
]}

Temple, CN ^{[1
]}

机构：

[1] Univ Leeds, Dept Chem, Leeds LS2 9JT, W Yorkshire, England

来源：

DALTON TRANSACTIONS | 2004年 / 12期

关键词：

D O I：

10.1039/b401877j

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We have successfully synthesised and characterised a number of. eta(1)- and eta(3)-triazacyclononane Rh-I and Rh-III derivatives. By using different reaction conditions, we have been able to convert one of the eta(1)-triazacyclononane complexes to an eta(3)-derivative. Also, we have observed a rare example of an addition of an organic fragment to a metal bound ligand to form a quaternary carbon centre.

引用

下载

页码：1841 / 1845

页数：5

共 50 条

[21] NOVEL RHODIUM ALKOXIDE COMPLEXES - STRUCTURE AND REACTIVITY
KEGLEY, SE
SCHAVERIEN, CJ
BERGMAN, RG
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1987, 193 : 405 - INOR
[22] Preparation and reactivity of macrocyclic rhodium(III) alkyl complexes
Carraher, Jack M.
Ellern, Arkady
Bakac, Andreja
INORGANICA CHIMICA ACTA, 2014, 409 : 254 - 258
[23] HETEROCYCLIC TELLURIUM COMPOUNDS AS LIGANDS - SOME COMPLEXES OF RHODIUM(III) AND RHODIUM(I)
ALRUBAIE, AZ
ALOBAIDI, YN
YOUSIF, LZ
POLYHEDRON, 1990, 9 (09) : 1141 - 1146
[24] RHODIUM(I) AND RHODIUM(III) COMPLEXES CONTAINING SCHIFF-BASE LIGANDS
MAGUE, JT
NUTT, MO
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1979, 166 (01) : 63 - 77
[25] RHODIUM (I)-DIETHYLDITHIOCARBAMATOALKENE AND IRIDIUM (I)-DIETHYLDITHIOCARBAMATOALKENE COMPLEXES AND THEIR USE IN PREPARATION OF RHODIUM (III)-DIETHYLDITHIOCARBAMATO AND IRIDIUM (III)-DIETHYLDITHIOCARBAMATO COMPLEXES
DECROON, MHJ
VANGAAL, HLM
VANDEREN.A
INORGANIC & NUCLEAR CHEMISTRY LETTERS, 1974, 10 (12): : 1081 - 1086
[26] Rhodium(III) and rhodium(II) complexes of novel bis(oxazoline) pincer ligands
Gerisch, M
Krumper, JR
Bergman, RG
Tilley, TD
ORGANOMETALLICS, 2003, 22 (01) : 47 - 58
[27] FORMATION OF RHODIUM(III) CARBONYLS IN NONAQUEOUS SOLVENTS, AND THEIR DECOMPOSITION BY WATER TO RHODIUM(I)
JAMES, BR
REMPEL, GL
NG, FTT
JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1969, (16): : 2454 - &
[28] Theoretical study of rhodium(III)-catalyzed hydrogenation of carbon dioxide into formic acid. Significant differences in reactivity among rhodium(III), rhodium(I), and ruthenium(II) complexes
Musashi, Y
Sakaki, S
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (25) : 7588 - 7603
[29] Synthesis and reactivity of trifluoromethyl isocyanide rhodium(I) complexes
Vicente, J
Gil-Rubio, J
Guerrero-Leal, J
Bautista, D
ORGANOMETALLICS, 2005, 24 (23) : 5634 - 5643
[30] COMPARISON OF PHOTOCHEMICAL REACTIVITY IN AZIDO COMPLEXES OF RHODIUM(III) AND COBALT(III)
FERRAUDI, G
ENDICOTT, JF
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1973, (AUG26): : 143 - 143

← 1 2 3 4 5 →