The formation, reactivity and interconversion of novel η1- and η3-triazacyclononane complexes of rhodium(I) and rhodium(III)

被引：10
|
作者：
Gott, AL [1 ]
McGowan, PC [1 ]
Temple, CN [1 ]
机构：
[1] Univ Leeds, Dept Chem, Leeds LS2 9JT, W Yorkshire, England
来源：
DALTON TRANSACTIONS | 2004年 / 12期
关键词：
D O I：
10.1039/b401877j
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
We have successfully synthesised and characterised a number of. eta(1)- and eta(3)-triazacyclononane Rh-I and Rh-III derivatives. By using different reaction conditions, we have been able to convert one of the eta(1)-triazacyclononane complexes to an eta(3)-derivative. Also, we have observed a rare example of an addition of an organic fragment to a metal bound ligand to form a quaternary carbon centre.
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页码：1841 / 1845
页数：5
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