The oxidizing of grain boundary defects in BaTiO3-based PTCR ceramics

被引:0
|
作者
Qi, JQ [1 ]
Zhang, NX [1 ]
Gui, ZL [1 ]
Li, LT [1 ]
机构
[1] Tsing Hua Univ, Dept Mat Sci & Engn, Beijing 100084, Peoples R China
关键词
oxidize; grain boundary; defects; PTCR; BaTiO3;
D O I
暂无
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The oxygen pressure during sintering influences greatly on the positive temperature coefficient resistance (PTCR) effect of BaTiO3-based ceramics. Using Bi2O3 vapor acting as excess donor resulted in the dense samples with the resistance jumping > 8 magnitude orders and the room temperature resistivity similar to100Ohm.cm. The oxidized-defects at grain boundary acting as trap centers, would be responsible for the PTCR effect in BaTiO, ceramics.
引用
收藏
页码:1407 / 1412
页数:6
相关论文
共 50 条
  • [21] VALENCE CHANGE OF MN IONS IN BATIO3-BASED PTCR MATERIALS
    LEE, JH
    KIM, SH
    CHO, SH
    JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1995, 78 (10) : 2845 - 2848
  • [22] Microwave sintering of BaTiO3-based ceramics
    Derling, S
    Abicht, HP
    JOURNAL OF MICROWAVE POWER AND ELECTROMAGNETIC ENERGY, 1996, 31 (04) : 221 - 227
  • [23] Influence of manganese on PTCR effect in BaTiO3-based ceramics doped with Bi2O3 vapor
    Qi, JQ
    Gui, ZL
    Wu, YJ
    Li, LT
    MATERIALS CHEMISTRY AND PHYSICS, 2002, 73 (01) : 97 - 100
  • [24] Effects of BNT Addition on the Microstructure and PTC Properties of La-Doped BaTiO3-Based PTCR Ceramics
    Wei, Jifeng
    Pu, Yongping
    Mao, Yuqin
    Wang, Jinfei
    FERROELECTRICS, 2010, 403 : 91 - 96
  • [25] Study on preparation and sinter-system of BaTiO3-based chip PTCR
    Liu, Huan
    Gong, Shu-Ping
    Zhou, Dong-Xiang
    Yadian Yu Shengguang/Piezoelectrics and Acoustooptics, 2005, 27 (03): : 267 - 269
  • [26] Synthesis of BaTiO3-based PTCR powders via a liquid phase process
    Zhou, DX
    Zheng, ZP
    Gong, SP
    Liu, H
    Hu, YX
    JOURNAL OF INORGANIC MATERIALS, 2005, 20 (03) : 593 - 598
  • [27] Simulation of the grain boundary effects in PTCR ceramics
    Fang, Chao
    Zhou, Dongxiang
    Liu, Huan
    Gong, Shuping
    HIGH-PERFORMANCE CERAMICS V, PTS 1 AND 2, 2008, 368-372 : 1692 - 1694
  • [28] Gas sensing characteristics of BaTiO3-based ceramics
    Park, K
    Seo, DJ
    MATERIALS CHEMISTRY AND PHYSICS, 2004, 85 (01) : 47 - 51
  • [29] Microstructure control of BaTiO3-based ceramics by the composition
    Konaka, H
    Sano, H
    Konoike, T
    Tomono, K
    ELECTROCERAMICS IN JAPAN III, 2000, 181-1 : 3 - 6
  • [30] BaTiO3-Based ceramics for tunable microwave applications
    Feteira, A
    Sinclair, DC
    Reaney, IM
    Somiya, Y
    Lanagan, MT
    JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2004, 87 (06) : 1082 - 1087