Building Light-Emitting Metal-Organic Frameworks by Post-Synthetic Modification

被引：51
|
作者：
Abdelhameed, Reda M. [1 ,2 ,3 ]
Ananias, Duarte [1 ]
Silva, Artur M. S. [2 ]
Rocha, Joao [1 ]
机构：
[1] Univ Aveiro, Dept Chem, CICECO, P-3810193 Aveiro, Portugal
[2] Univ Aveiro, Dept Chem, QOPNA, P-3810193 Aveiro, Portugal
[3] Natl Res Ctr, Appl Organ Chem Dept, Giza 12622, Egypt
来源：
CHEMISTRYSELECT | 2017年 / 2卷 / 01期
关键词：
Luminescence; Metal-Organic Frameworks; Optical centre; Post-synthetic modification; LANTHANIDE COMPLEXES;
D O I：
10.1002/slct.201601751
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Ln(3+)-bearing Metal-Organic Frameworks (MOFs) are attracting much attention because of their unique luminescence properties and the possibility of fine-tuning the metal coordination spheres by post-synthetic modification (PSM). Here, we report PSM of the well-known IRMOF-3 by reaction with methyl 3chloro-3-oxopropanoate and pyridine-2,6-dicarbonyl dichloride affording, respectively, IRMOF-3-CM and IRMOF-3-PY. (HNMR)-H-1 of the digested modified samples showed ca. 100% conversion of the amino group. The pendant groups of PSM IRMOF-3 were subsequently used to coordinate Eu+3 and Tb3+ and the luminescence properties of the materials studied.
引用
收藏
页码：136 / 139
页数：4
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