Building Light-Emitting Metal-Organic Frameworks by Post-Synthetic Modification

被引：51

作者：

Abdelhameed, Reda M. ^{[1
,2
,3
]}

Ananias, Duarte ^{[1
]}

Silva, Artur M. S. ^{[2
]}

Rocha, Joao ^{[1
]}

机构：

[1] Univ Aveiro, Dept Chem, CICECO, P-3810193 Aveiro, Portugal

[2] Univ Aveiro, Dept Chem, QOPNA, P-3810193 Aveiro, Portugal

[3] Natl Res Ctr, Appl Organ Chem Dept, Giza 12622, Egypt

来源：

CHEMISTRYSELECT | 2017年 / 2卷 / 01期

关键词：

Luminescence; Metal-Organic Frameworks; Optical centre; Post-synthetic modification; LANTHANIDE COMPLEXES;

D O I：

10.1002/slct.201601751

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ln(3+)-bearing Metal-Organic Frameworks (MOFs) are attracting much attention because of their unique luminescence properties and the possibility of fine-tuning the metal coordination spheres by post-synthetic modification (PSM). Here, we report PSM of the well-known IRMOF-3 by reaction with methyl 3chloro-3-oxopropanoate and pyridine-2,6-dicarbonyl dichloride affording, respectively, IRMOF-3-CM and IRMOF-3-PY. (HNMR)-H-1 of the digested modified samples showed ca. 100% conversion of the amino group. The pendant groups of PSM IRMOF-3 were subsequently used to coordinate Eu+3 and Tb3+ and the luminescence properties of the materials studied.

引用

页码：136 / 139

页数：4

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