Highly effective catalysts for the addition polymerization of norbornene: zerovalent-nickel complex/H2O/BF3•OEt2

被引：8
|
作者：
Tkach, V. S. [1 ]
Suslov, D. S. [1 ]
Myagmarsuren, G. [2 ]
Gubaydulina, O. V. [1 ]
Bykov, M. V. [1 ]
Umanets, V. A. [1 ]
机构：
[1] Irkutsk State Univ, Irkutsk 664003, Russia
[2] Natl Univ Mongolia, Ulaanbaatar 210646, Mongolia
来源：
CATALYSIS COMMUNICATIONS | 2009年 / 10卷 / 14期
基金：
俄罗斯基础研究基金会;
关键词：
Boron trifluoride; Polymerization; Nickel; Norbornene; ACTIVATION; COMPLEXES;
D O I：
10.1016/j.catcom.2009.06.006
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A series of nickel(0)/BF3 center dot OEt2 catalyst systems have been tested in the addition polymerization of norbornene. Experimental evidence for Ni(II) hydride formation as a result of interaction between Ni(PPh3)(4) and BF3 center dot OEt2 in the presence of controlled amounts of H2O was obtained. (c) 2009 Elsevier B.V. All rights reserved.
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页码：1813 / 1815
页数：3
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