Highly effective catalysts for the addition polymerization of norbornene: zerovalent-nickel complex/H2O/BF3•OEt2

被引：8
|
作者：
Tkach, V. S. [1 ]
Suslov, D. S. [1 ]
Myagmarsuren, G. [2 ]
Gubaydulina, O. V. [1 ]
Bykov, M. V. [1 ]
Umanets, V. A. [1 ]
机构：
[1] Irkutsk State Univ, Irkutsk 664003, Russia
[2] Natl Univ Mongolia, Ulaanbaatar 210646, Mongolia
来源：
CATALYSIS COMMUNICATIONS | 2009年 / 10卷 / 14期
基金：
俄罗斯基础研究基金会;
关键词：
Boron trifluoride; Polymerization; Nickel; Norbornene; ACTIVATION; COMPLEXES;
D O I：
10.1016/j.catcom.2009.06.006
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A series of nickel(0)/BF3 center dot OEt2 catalyst systems have been tested in the addition polymerization of norbornene. Experimental evidence for Ni(II) hydride formation as a result of interaction between Ni(PPh3)(4) and BF3 center dot OEt2 in the presence of controlled amounts of H2O was obtained. (c) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码：1813 / 1815
页数：3
相关论文
共 50 条
  • [21] Influence of alcohols on the formation of the nickel complexes active in ethene oligomerization in the catalytic system Ni(PPh3)4/BF3•OEt2
    Saraev, VV
    Kraikivskii, PB
    Zelinskiy, SN
    Matveev, DA
    Vilms, AI
    Rohin, AV
    Lammertsma, K
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2005, 236 (1-2) : 125 - 131
  • [22] BF3•OEt2 catalyzed decarbonylative arylation/C-H functionalization of diazoamides with arylaldehydes: synthesis of substituted 3-aryloxindoles
    Muthusamy, Sengodagounder
    Prabu, Ammasi
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2022, 20 (11) : 2209 - 2216
  • [23] The reaction of BF3 with H2O:: Infrared spectrum of BF2OH trapped in solid neon
    Jacox, ME
    Irikura, KK
    Thompson, WE
    JOURNAL OF CHEMICAL PHYSICS, 2000, 113 (14): : 5705 - 5715
  • [24] Highly Regioselective Addition of Organozinc Reagents to 2-Oxo-1,2-dihydropyrimidine-5-carboxylates Activated by BF3•OEt2: Synthesis of 2-Oxo-1,2,3,4-tetrahydropyrimidine-5-carboxylates
    Singh, Kamaljit
    Chopra, Rakesh
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2013, 2013 (27) : 6124 - 6129
  • [25] Naturally-Derived Amphiphilic Polystyrenes Prepared by Aqueous Controlled/Living Cationic Polymerization and Copolymerization of Vinylguaiacol with R-OH/BF3•OEt2
    Takeshima, Hisaaki
    Satoh, Kotaro
    Kamigaito, Masami
    POLYMERS, 2018, 10 (12):
  • [26] NUCLEAR MAGNETIC RESONANCE STUDIES OF BF3 ADDITION COMPOUNDS .1. EXCHANGE OF BF3 BETWEEN (CH3)2O.BF3 AND (C2H5)2O.BF3
    RUTENBERG, AC
    PALKO, AA
    DRURY, JS
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1963, 85 (18) : 2702 - &
  • [27] BF3 ⋅ OEt2 and Visible Light-Controlled [3,3]- or [1,3]-Rearrangement of Quinazolinone N-O Aryl Moieties
    Nie, Shu-Min
    Cheng, Lu-Min
    Chen, Chun-Hua
    Liang, Cui
    Pan, Cheng-Xue
    Mo, Dong-Liang
    ADVANCED SYNTHESIS & CATALYSIS, 2024, 366 (09) : 2056 - 2062
  • [28] BF3•OEt2 catalyzed S-H insertion reactions of α-diazo imidamides and enolizable thioamides under metal-free conditions
    Mangali, Rofin
    Muthusamy, Sengodagounder
    NEW JOURNAL OF CHEMISTRY, 2022, 46 (48) : 23173 - 23178
  • [29] NUCLEAR MAGNETIC RESONANCE STUDIES OF BF3 ADDITION COMPOUNDS .2. EXCHANGE OF BF3 BETWEEN C6H5OCH3.BF3 + (C2H5)2O.BF3
    RUTENBERG, AC
    DRURY, JS
    PALKO, AA
    JOURNAL OF PHYSICAL CHEMISTRY, 1964, 68 (04): : 976 - &
  • [30] On the Reactivity of RSnCl and RSiMe3 {R=4-tBu-2,6-[P(O)(OiPr)2]2C6H2} towards BF3•OEt2: Competing Lewis Acidities
    Wagner, Michael
    Lutter, Michael
    Dietz, Christina
    Prosenc, Marc H.
    Jurkschat, Klaus
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2015, (12) : 2152 - 2158
12345