Chloro(nitrato)[1,4,7-tris(4-vinyl)benzyl-1,4,7-triazacyclononane]copper(II)

被引:4
|
作者
Deschamps, JR
Hartshorn, CM
Singh, A
Chang, EL
机构
[1] USN, Res Lab, Struct Matter Lab, Washington, DC 20375 USA
[2] Geocenters Inc, Ft Washington, MD 20744 USA
[3] USN, Res Lab, Ctr Biomol Sci & Engn, Washington, DC 20375 USA
关键词
D O I
10.1107/S1600536802011613
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title compound, [CuCl(NO3)(C33H39N3)] or Cu([9]ane(Nvbz)(3) NO3Cl, is the polymerizable form of a potent metal-chelator complex that catalyses the hydrolysis of phosphate esters. The coordination geometry around the Cu atom is square pyramidal. The structure has a similar conformation to the parent catalyst Cu([9]aneN(3))Cl-2, showing that the extensive functionalization does not significantly distort the metal-complex geometry.
引用
收藏
页码:m396 / m398
页数:3
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