Chloro(nitrato)[1,4,7-tris(4-vinyl)benzyl-1,4,7-triazacyclononane]copper(II)

被引:4
|
作者
Deschamps, JR
Hartshorn, CM
Singh, A
Chang, EL
机构
[1] USN, Res Lab, Struct Matter Lab, Washington, DC 20375 USA
[2] Geocenters Inc, Ft Washington, MD 20744 USA
[3] USN, Res Lab, Ctr Biomol Sci & Engn, Washington, DC 20375 USA
关键词
D O I
10.1107/S1600536802011613
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title compound, [CuCl(NO3)(C33H39N3)] or Cu([9]ane(Nvbz)(3) NO3Cl, is the polymerizable form of a potent metal-chelator complex that catalyses the hydrolysis of phosphate esters. The coordination geometry around the Cu atom is square pyramidal. The structure has a similar conformation to the parent catalyst Cu([9]aneN(3))Cl-2, showing that the extensive functionalization does not significantly distort the metal-complex geometry.
引用
收藏
页码:m396 / m398
页数:3
相关论文
共 50 条
  • [21] Lanthanide Complexes with 1,4,7-Trimethyl-1,4,7-triazacyclononane
    Degtyareva, S. S.
    Bardonov, D. A.
    Lysenko, K. A.
    Minyaev, M. E.
    Nifant'ev, I. E.
    Roitershtein, D. M.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2024, 50 (04) : 292 - 299
  • [22] μ-1,5-dicyanarnido-bis[chloro(1,4,7-triazacyclononane)copper(II)] perchlorate
    Wang, ZD
    Han, W
    Yan, SP
    Liao, DZ
    Jiang, ZH
    Cheng, P
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2004, 60 : M1137 - M1138
  • [23] Diastereomeric discrimination in 1,4,7-tris((S)-2-hydroxypropyl)-1,4,7-triazacyclononane and its lithium(I), sodium(I) and zinc(II) complexes
    Weeks, JM
    Buntine, MA
    Lincoln, SF
    Tiekink, ERT
    Wainwright, KP
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2001, (14): : 2157 - 2163
  • [24] Trichloro(1,4,7-trimethyl-1,4,7-triazacyclononane)chromium(III)
    Klitgaard, SK
    Magnussen, M
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : M2616 - M2617
  • [25] The hexadentate ligand 1,4,7-tris(o-aminobenzyl)-1,4,7-triazacyclononane and its complexes with zinc(II), cadmium(II), and mercury(II) in solution and in the solid state
    Schlager, O
    Wieghardt, K
    Grondey, H
    Rufinska, A
    Nuber, B
    INORGANIC CHEMISTRY, 1995, 34 (26) : 6440 - 6448
  • [27] TRIAMMINE(1,4,7-TRIAZACYCLOALKANE)COBALT(III) AND [(R)-2-METHYL-1,4,7-TRIAZACYCLONONANE] (1,4,7-TRIAZACYCLONONANE)COBALT(III)
    NONOYAMA, M
    SAKAI, K
    INORGANICA CHIMICA ACTA-ARTICLES, 1983, 72 (01): : 57 - 60
  • [28] Formation and structural studies of iron(III) and ruthenium(II) complexes of 1,4,7-triazacyclononane and N-monofunctionalised 1,4,7-triazacyclononane
    Gott, AL
    McGowan, PC
    Podesta, TJ
    Tate, CW
    INORGANICA CHIMICA ACTA, 2004, 357 (03) : 689 - 698
  • [29] Synthesis, characterization, and acidity of ruthenium dihydrogen complexes with 1,4,7-triazacyclononane, 1,4,7-trimethyl-1,4,7-triazacyclononane, and hydrotris(pyrazolyl)borato ligands
    Ng, SM
    Fang, YQ
    Lau, CP
    Wong, WT
    Jia, GC
    ORGANOMETALLICS, 1998, 17 (10) : 2052 - 2059
  • [30] Efficient Synthesis of 1,4,7-Triazacyclononane and 1,4,7-Triazacyclononane-Based Bifunctional Chelators for Bioconjugation
    Desogere, Pauline
    Rousselin, Yoann
    Poty, Sophie
    Bernhard, Claire
    Goze, Christine
    Boschetti, Frederic
    Denat, Franck
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2014, 2014 (35) : 7831 - 7838