Frustrated Lewis pair chemistry of carbon, nitrogen and sulfur oxides

被引：352

作者：

Stephan, Douglas W. ^{[1
]}

Erker, Gerhard ^{[2
]}

机构：

[1] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada

[2] Univ Munster, Inst Organ Chem, D-48149 Munster, Germany

来源：

CHEMICAL SCIENCE | 2014年 / 5卷 / 07期

基金：

加拿大自然科学与工程研究理事会; 欧洲研究理事会;

关键词：

FREE CATALYTIC-HYDROGENATION; SMALL-MOLECULE ACTIVATION; N-HETEROCYCLIC CARBENE; NITRIC-OXIDE; C-H; CO2; REDUCTION; COMPLEXES; MONOXIDE; BORANE;

D O I：

10.1039/c4sc00395k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Frustrated Lewis pairs have been used to activate a variety of small molecules. In this review we focus on the recent chemistry of FLPs with CO2, CO, N2O, NO and SO2. While FLP capture of these small molecule is achieved in all of these cases, subsequent applications of the products include stoichiometric and catalytic reductions of CO2, C-O bond scission of CO and use of FLP-NO radicals in polymerization.

引用

页码：2625 / 2641

页数：17

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