New Organoboranes in "Frustrated Lewis Pair" Chemistry

被引：5

作者：

Lu, Zhenpin ^{[1
]}

Ye, Hongyan ^{[1
]}

Wang, Huadong ^{[1
]}

机构：

[1] Fudan Univ, Shanghai Key Lab Mol Catalysis & Innovat Mat, Dept Chem, Shanghai 200433, Peoples R China

来源：

FRUSTRATED LEWIS PAIRS II: EXPANDING THE SCOPE | 2013年 / 334卷

关键词：

Boranes; Dihydrogen; Hydrogenation;

D O I：

10.1007/128_2012_382

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The chemistry of "frustrated Lewis pairs" (FLPs) has become a rapidly evolving field since it was introduced 6 years ago. It offers new strategies for small molecule activation and organic synthesis which have long been dominated by transition metals. This chapter focuses on the recent development of organoborane compounds and their applications in FLP chemistry. Modifying the organoboranes along with optimizing the Lewis base partners results in a wide range of reactivities, such as small molecule activation and hydrogenation catalysis.

引用

页码：59 / 80

页数：22

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