Coupling of Carbon Monoxide with Nitrogen Monoxide at a Frustrated Lewis Pair Template

被引：24
|
作者：
Ye, Ke-Yin [1 ]
Kehr, Gerald [1 ]
Daniliuc, Constantin G. [1 ]
Liu, Lei [2 ]
Grimme, Stefan [2 ]
Erker, Gerhard [1 ]
机构：
[1] Univ Munster, Organ Chem Inst, Corrensstr 40, D-48149 Munster, Germany
[2] Univ Bonn, Inst Phys & Theoret Chem, Mulliken Ctr Theoret Chem, Beringstr 4, D-53115 Bonn, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2016年 / 55卷 / 32期
基金：
欧洲研究理事会;
关键词：
boron; carbon monoxide; frustrated Lewis pairs; nitric oxide; phosphorus; NITRIC-OXIDE; NITROXYL HNO; BASIS-SETS; CHEMISTRY; ACCURATE; DESIGN;
D O I：
10.1002/anie.201603760
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Coupling of carbon monoxide with nitrogen monoxide was achieved at a frustrated Lewis pair template. This unique reaction uses hydride as an auxiliary, which reductively activates carbon monoxide at the frustrated Lewis pair. The CO/NO coupling reaction then takes place through a pathway involving a radical reaction in which the hydrogen atom auxiliary is eventually removed again.
引用
收藏
页码：9216 / 9219
页数：4
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