Synthesis, Crystal Structure and Luminescent Properties of One Cadmium(II) Coordination Polymer with Mixed Thiocyanate and Quinoline Ligands

被引：8
|
作者：
Bai, Yan [1 ]
Gao, Hui [1 ]
Dang, Dong-Bin [1 ]
Hu, Xue-Fu [1 ]
Guo, Xiang-Yang [1 ]
机构：
[1] Henan Univ, Sch Chem & Chem Engn, Inst Mol & Crystal Engn, Kaifeng 475004, Peoples R China
来源：
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2009年 / 39卷 / 09期
基金：
中国国家自然科学基金;
关键词：
Cadmium(II) complex; crystal structure; luminescent properties; thiocyanato bridged; ELEMENTAL COPPER; ETHYLENEDIAMINE; COMPLEX; CHAIN;
D O I：
10.1080/15533170903324650
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel Cd(II) coordination polymer [Cd(SCN)2(ql)2]2 center dot (CH3CN)2 (ql = quinoline) has been synthesized and characterized by IR, UV, elemental analysis and X-ray crystallography. Cd(II) atom has an distorted octahedral environment with an N4S2 donor set. A pair of 1,3--SCN- anions bridge two adjacent Cd(II) centers to form one dimension chain structure. A 1D structure is held together with its neighboring ones via - stacking interactions to form a 3D supramolecular structure. The luminescent properties of the title complex at room temperature were investigated.
引用
收藏
页码：512 / 515
页数：4
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