Synthesis, crystal structure and magnetic properties of manganese(II) coordination polymer from isonicotinate and amino-tetrazole mixed-ligands

被引:10
|
作者
Liu, Dong-Sheng [1 ]
Chen, Wen-Tong [1 ]
Huang, Jian-Gen [1 ]
Wang, Ji-Wei [1 ]
Sui, Yan [1 ]
机构
[1] Jinggangshan Univ, Sch Chem & Chem Engn, Inst Appl Chem, Jian 343009, Jiangxi, Peoples R China
关键词
Coordination polymers; Topological network; Mixed-ligand; Tetrazole; Magnetic properties; METAL-ORGANIC FRAMEWORK; HYDROTHERMAL SYNTHESIS; DELTA-CHAINS; AZIDE; CARBOXYLATE; MN(II); CO(II); TRINUCLEAR;
D O I
10.1016/j.inoche.2013.08.037
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A new 3D coordination polymer, Mn-2(atz)(isonic)(OH)(Cl)](n) (1), was synthesized hydrothermally from mixed-ligands of Hatz (Hatz = 5-amino-tetrazolate) and Hisonic (Hisonic = isonicotinate) and corresponding metal salts. It was characterized by IR spectra, elemental and thermal analysis, single crystal and powder X-ray diffraction. Variable temperature magnetic investigations indicate that compound 1 exhibits typical antiferromagnetic behaviors. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:174 / 178
页数:5
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