Synthesis, crystal structure and magnetic properties of manganese(II) coordination polymer from isonicotinate and amino-tetrazole mixed-ligands

被引：10

作者：

Liu, Dong-Sheng ^{[1
]}

Chen, Wen-Tong ^{[1
]}

Huang, Jian-Gen ^{[1
]}

Wang, Ji-Wei ^{[1
]}

Sui, Yan ^{[1
]}

机构：

[1] Jinggangshan Univ, Sch Chem & Chem Engn, Inst Appl Chem, Jian 343009, Jiangxi, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2013年 / 36卷

关键词：

Coordination polymers; Topological network; Mixed-ligand; Tetrazole; Magnetic properties; METAL-ORGANIC FRAMEWORK; HYDROTHERMAL SYNTHESIS; DELTA-CHAINS; AZIDE; CARBOXYLATE; MN(II); CO(II); TRINUCLEAR;

D O I：

10.1016/j.inoche.2013.08.037

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new 3D coordination polymer, Mn-2(atz)(isonic)(OH)(Cl)](n) (1), was synthesized hydrothermally from mixed-ligands of Hatz (Hatz = 5-amino-tetrazolate) and Hisonic (Hisonic = isonicotinate) and corresponding metal salts. It was characterized by IR spectra, elemental and thermal analysis, single crystal and powder X-ray diffraction. Variable temperature magnetic investigations indicate that compound 1 exhibits typical antiferromagnetic behaviors. (C) 2013 Elsevier B.V. All rights reserved.

引用

页码：174 / 178

页数：5

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