Synthesis and crystal structures of two trigonal bipyramidal Sb(V) compounds, R2SbBr3 and R3Sb(S2PPh2)2 (R = Me3SiCH2)

被引：5
|
作者：
Silvestru, A
Breunig, HJ
Stanciu, M
Rösler, R
Lork, E
机构：
[1] Univ Bremen, Inst Anorgan & Phys Chem, Fachbereich 2, D-28334 Bremen, Germany
[2] Univ Babes Bolyai, Fac Chim, RO-3400 Cluj Napoca, Romania
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1999年 / 588卷 / 02期
关键词：
antimony; phosphorus; X-ray structure;
D O I：
10.1016/S0022-328X(99)00385-X
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Addition of Br-2 to R2SbBr (R = Me3SiCH2) gives R2SbBr3 (1). R3SbBr2 reacts with NH4S2PPh2 to form R3Sb(S2PPh2)(2), (2). The structures of 1 and 2 have been determined by single-crystal X-ray diffraction. (C) 1999 Elsevier Science S.A. All rights reserved.
引用
收藏
页码：256 / 259
页数：4
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