Synthesis and crystal structures of two trigonal bipyramidal Sb(V) compounds, R2SbBr3 and R3Sb(S2PPh2)2 (R = Me3SiCH2)

被引：5

作者：

Silvestru, A

Breunig, HJ

Stanciu, M

Rösler, R

Lork, E

机构：

[1] Univ Bremen, Inst Anorgan & Phys Chem, Fachbereich 2, D-28334 Bremen, Germany

[2] Univ Babes Bolyai, Fac Chim, RO-3400 Cluj Napoca, Romania

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1999年 / 588卷 / 02期

关键词：

antimony; phosphorus; X-ray structure;

D O I：

10.1016/S0022-328X(99)00385-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Addition of Br-2 to R2SbBr (R = Me3SiCH2) gives R2SbBr3 (1). R3SbBr2 reacts with NH4S2PPh2 to form R3Sb(S2PPh2)(2), (2). The structures of 1 and 2 have been determined by single-crystal X-ray diffraction. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

页码：256 / 259

页数：4

共 50 条

[31] SILYLATED DIPHOSPHITE COMPLEXES OF MOLYBDENUM - CRYSTAL-STRUCTURES OF THE COMPOUNDS MO(CO)4[P(OME)2O]2SIR2R3 (R2 = R3 = PH OR R2 = ME, R3 = PH)
SUM, V
KEE, TP
THORNTONPETT, M
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1992, 438 (1-2) : 89 - 98
[32] SYNTHESIS AND STRUCTURE OF THE 1ST ALKYL-BRIDGED DOUBLE LADDER - [R(CL)SN(CH2)3SN(CL)R]O)4 (R = ME3SICH2)
DAKTERNIEKS, D
JURKSCHAT, K
SCHOLLMEYER, D
WU, H
ORGANOMETALLICS, 1994, 13 (10) : 4121 - 4123
[33] Synthesis and characterization of sterically hindered alkylaluminum-phosphorus and -arsenic compounds.: X-ray crystal structures of (Me3ECH2)3Al•E′(SiMe3)3 (E = Si, E′ = As; E = C, E′ = P, As), (Me3SiCH2)2(Br)Al•P(SiMe3)3, and [(Me3SiCH2)(X)AlE(SiMe3)2]2 (X = Br, E = P, As; X = Me3SiCH2, E = As)
Wells, RL
Foos, EE
Rheingold, AL
Yap, GPA
Liable-Sands, LM
White, PS
ORGANOMETALLICS, 1998, 17 (13) : 2869 - 2875
[34] Sb8R4, R = (Me3Si)(2)CH - A polycyclic organostibane
Breunig, HJ
Rosler, R
Lork, E
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (20): : 2237 - 2238
[35] PREPARATION AND CRYSTAL-STRUCTURE OF [(ME3SICH2)2INP(H)AD]2
DEMBOWSKI, U
ROESKY, HW
POHL, E
HERBSTIRMER, R
STALKE, D
SHELDRICK, GM
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1992, 611 (05): : 92 - 94
[36] Coupling of alkynes promoted by Ru(CO)3(PPh3)2 and carbon dioxide:: syntheses and structures of (η4-C4R2R2′CO) Ru(CO)2(PPh3) (R = R′ = Ph; R = Ph, R′ = CCPh) and {Ph2C4(CCPh)2}Ru(CO)(PPh3)2
Yamazaki, S
Taira, Z
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1999, 578 (1-2) : 61 - 67
[37] Syntheses and crystal structures of [μ-(Me3SiCH2Sb)5-Sb1,Sb3-{W(CO)5}2] and [{(Me3Si)2CHSb}3Fe(CO)4] -: Two cyclic complexes with antimony ligands
Balázs, G
Breunig, HJ
Lork, E
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2001, 627 (08): : 1855 - 1858
[38] Synthesis and crystal structures of the silylated lambda(5)-phosphazenes R-C(CH2PPh2NSiMe3)(3) with R = H and CH3
Schlecht, S
Faza, N
Massa, W
Weller, F
Dehnicke, K
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1997, 623 (11): : 1739 - 1743
[39] Spacial configuration of compounds of the type R3PX2, R3AsX2, R3SbX2 and R3BiX2
Jensen, KA
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1943, 250 (3/4): : 257 - 267
[40] SYNTHESIS AND MOLECULAR-STRUCTURES OF R(ME3CCH2)2IN-CENTER-DOT-E(SIME3)3 (R=ME3CCH2, E=P OR AS R=ME, E=P)
SELF, MF
MCPHAIL, AT
JONES, LJ
WELLS, RL
POLYHEDRON, 1994, 13 (04) : 625 - 634

← 1 2 3 4 5 →