Sputtered rutile stoichiometric TiO2 nanocrystalline films

被引:9
|
作者
Vale, A.
Chaure, N.
Simonds, M.
Ray, A. K.
Bricklebank, N.
机构
[1] Univ London, Queen Mary, Dept Mat, Nanotechnol Res Labs, London E1 4NS, England
[2] Sheffield Hallam Univ, Sch Engn, Sheffield S1 1WB, S Yorkshire, England
[3] Univ Dublin Trinity Coll, Dept Phys, Dublin 2, Ireland
[4] Sheffield Hallam Univ, Mat Res Inst, Sheffield S1 1WB, S Yorkshire, England
关键词
D O I
10.1007/s10854-006-0034-z
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
Titanium dioxide (TiO2) films were prepared at room temperature on silicon and glass substrates using DC reactive magnetron sputtering at the rate of 0.1 nms(-1) from a pure metal Ti target. X-ray diffraction (XRD) studies on freshly prepared samples showed a purely rutile phase. It is found from AFM that annealing of fresh TiO2 films at 550 degrees C for 30 min produced an increase in grain size by a factor of at least 1.5. X-ray photoelectron spectroscopies (XPS) gives correct ratio for purely TiO2 stoichiometry. Optical band gap was estimated to be 3.2 eV from UV-vis transmission spectra.
引用
收藏
页码:851 / 855
页数:5
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