New chiral Schiff base as a tridentate ligand for catalytic enantioselective addition of diethylzinc to aldehydes

被引：69

作者：

Tanaka, Takanori ^{[1
]}

Yasuda, Yorinobu ^{[1
]}

Hayashi, Masahiko ^{[1
]}

机构：

[1] Kobe Univ, Fac Sci, Dept Chem, Kobe, Hyogo 6578501, Japan

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2006年 / 71卷 / 18期

关键词：

D O I：

10.1021/jo060964u

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We have developed new chiral Schiff base catalysts for the enantioselective addition of diethylzinc reagents to aldehydes. The reaction of benzaldehyde with diethylzinc in the presence of 1 mol % of the chiral Schiff base catalyst proceeded to afford 1-phenyl-1-propanol in 96% enantiomeric excess (ee).

引用

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页码：7091 / 7093

页数：3

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