Syntheses and characteristics of the heterobimetalorganics of the silicon with the 2-(dimethylaminomethyl)ferrocenyl ligand FcN (η5-C5H5)Fe[η5-C5H3(CH2NMe2)]-

被引：1
|
作者：
Jacob, K
Görls, H
Lorenz, V
机构：
[1] Univ Halle Wittenberg, Inst Anorgan Chem, D-06120 Halle An Der Saale, Germany
[2] Univ Jena, Inst Anorgan & Analyt Chem, D-6900 Jena, Germany
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2004年 / 630卷 / 05期
关键词：
heterobimetallics; ferrocene; silicon; hydrolysis; crystal structure;
D O I：
10.1002/zaac.200400001
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The heterobimetallic lithiumorganyl [2-(dimethylaminomethyl)ferrocenyl] lithium, LiFcN, reacts with silicon(IV)-chlorid, SiCl4, under the formation of heterobimetallic silicon(IV) organyl [(FcN)(3)SiCl] (1). The hetero bimetallic organosilanol [(FcN)(3)SiOH] (2) is formed at hydrolysis of 1. A detailed characterization of the defined compounds 1 and 2 was carried out by NMR- rsp. mass-spectrometry and by crystal X-ray analysis of 2.
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页码：752 / 755
页数：4
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