Syntheses and characteristics of the heterobimetalorganics of the silicon with the 2-(dimethylaminomethyl)ferrocenyl ligand FcN (η5-C5H5)Fe[η5-C5H3(CH2NMe2)]-

被引：1

作者：

Jacob, K

Görls, H

Lorenz, V

机构：

[1] Univ Halle Wittenberg, Inst Anorgan Chem, D-06120 Halle An Der Saale, Germany

[2] Univ Jena, Inst Anorgan & Analyt Chem, D-6900 Jena, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2004年 / 630卷 / 05期

关键词：

heterobimetallics; ferrocene; silicon; hydrolysis; crystal structure;

D O I：

10.1002/zaac.200400001

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The heterobimetallic lithiumorganyl [2-(dimethylaminomethyl)ferrocenyl] lithium, LiFcN, reacts with silicon(IV)-chlorid, SiCl4, under the formation of heterobimetallic silicon(IV) organyl [(FcN)(3)SiCl] (1). The hetero bimetallic organosilanol [(FcN)(3)SiOH] (2) is formed at hydrolysis of 1. A detailed characterization of the defined compounds 1 and 2 was carried out by NMR- rsp. mass-spectrometry and by crystal X-ray analysis of 2.

引用

页码：752 / 755

页数：4

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