High-Concentration Na Doping of SrRuO3 and CaRuO3

被引：14
|
作者：
Seki, Hayato [1 ]
Yamada, Ryuta [1 ]
Saito, Takashi [1 ]
Kennedy, Brendan J. [2 ]
Shimakawa, Yuichi [1 ,3 ]
机构：
[1] Kyoto Univ, Inst Chem Res, Kyoto 6110011, Japan
[2] Univ Sydney, Sch Chem, Sydney, NSW 2006, Australia
[3] Japan Sci & Technol Agcy, CREST, Kyoto 6110011, Japan
来源：
INORGANIC CHEMISTRY | 2014年 / 53卷 / 09期
基金：
日本科学技术振兴机构; 澳大利亚研究理事会;
关键词：
TRANSPORT-PROPERTIES; TERNARY;
D O I：
10.1021/ic500265t
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The Na-doped perovskite-structure ruthenates Sr1-xNaxRuO3 and Ca1-yNayRuO3 were prepared by high-pressure synthesis, which enables us to go beyond the previously reported Na doping limits and substitute Na for over 50% of the Sr in SrRuO3 and the Ca in CaRuO3. Gradual and systematic changes in the crystal structures were observed, and the decreases in the Ru-O bond lengths confirmed the Na substitution at the A site caused hole doping to Ru4+ at the B site. In contrast to what has been previously reported, Sr1-xNaxRuO3 showed metallic conductivity. Magnetic properties were influenced by the Na substitution, but no long-range antiferromagnetic behavior was observed in Ca1-yNayRuO3.
引用
收藏
页码：4579 / 4584
页数：6
相关论文
共 50 条
  • [41] First principles investigation of Na doping effects on the structural, magnetic, and electronic properties in SrRuO3
    Jiao, Peng
    Liu, Yi
    Wang, Xueye
    Chen, Jingjing
    COMPUTATIONAL MATERIALS SCIENCE, 2013, 69 : 284 - 298
  • [42] SrRuO3/SrTiO3/SrRuO3 heterostructures for magnetic tunnel junctions
    Herranz, G
    Martínez, B
    Fontcuberta, J
    Sánchez, F
    García-Cuenca, MV
    Ferrater, C
    Varela, M
    JOURNAL OF APPLIED PHYSICS, 2003, 93 (10) : 8035 - 8037
  • [43] Comparative angle-resolved photoemission spectroscopy study of CaRuO3 and SrRuO3 thin films: Pronounced spectral weight transfer and possible precursor of lower Hubbard band
    Yang, H. F.
    Fan, C. C.
    Liu, Z. T.
    Yao, Q.
    Li, M. Y.
    Liu, J. S.
    Jiang, M. H.
    Shen, D. W.
    PHYSICAL REVIEW B, 2016, 94 (11)
  • [44] High-temperature phases of SrRuO3
    Kennedy, BJ
    Hunter, BA
    PHYSICAL REVIEW B, 1998, 58 (02): : 653 - 658
  • [45] SrRuO3/SrTiO3/SrRuO3 heterostructures for magnetic tunnel junctions
    Herranz, G. (gherranz@icmab.es), 1600, American Institute of Physics Inc. (93):
  • [46] Reliability of SrRuO3/SrTiO3/SrRuO3 Stacks for DRAM Applications
    Kupke, S.
    Knebel, S.
    Schroeder, U.
    Schmelzer, S.
    Boettger, U.
    Mikolajick, T.
    IEEE ELECTRON DEVICE LETTERS, 2012, 33 (12) : 1699 - 1701
  • [47] Nonstoichiometric composition and densification of CaRuO3 by SPS
    Keawprak, Nittaya
    Tu, Rong
    Goto, Takashi
    INNOVATION IN CERAMICS SCIENCE AND ENGINEERING, 2007, 352 : 251 - +
  • [48] High pressure structural studies on SrRuO3
    Jacobsen, M. K.
    Kumar, R. S.
    Cao, G.
    Neumeier, J. J.
    Cornelius, A. L.
    JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2008, 69 (09) : 2237 - 2239
  • [49] Epitaxial SrRuO3/BiFeO3/SrRuO3 heterostructure sputtered at low temperature
    Zhao, Q. X.
    Ma, J. K.
    Wei, D. Y.
    Wang, K. M.
    Li, X. H.
    Zhang, X. Y.
    Liu, B. T.
    JOURNAL OF CRYSTAL GROWTH, 2011, 316 (01) : 71 - 74
  • [50] Tailoring the electronic properties of SrRuO3 films in SrRuO3/LaAlO3 superlattices
    Liu, Z. Q.
    Ming, Y.
    Lu, W. M.
    Huang, Z.
    Wang, X.
    Zhang, B. M.
    Li, C. J.
    Gopinadhan, K.
    Zeng, S. W.
    Annadi, A.
    Feng, Y. P.
    Venkatesan, T.
    Ariando
    APPLIED PHYSICS LETTERS, 2012, 101 (22)
12345