Oxidation and addition of Dihalocarbenes to β-himachalene

被引：51
|
作者：
Eljamili, H
Auhmani, A [1 ]
Dakir, M
Lassaba, E
Benharref, A
Pierrot, M
Chiaroni, A
Riche, C
机构：
[1] Fac Sci Semlalia, Dept Chim, Lab Chim Subst Nat & Heterocycles, Marrakech, Morocco
[2] ICSN, CNRS, F-91198 Gif Sur Yvette, France
[3] Ctr Sci St Jerome, LBS UMR 6517 2, F-13397 Marseille 20, France
来源：
TETRAHEDRON LETTERS | 2002年 / 43卷 / 37期
关键词：
D O I：
10.1016/S0040-4039(02)01407-7
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Reaction of beta-himachalene with one equivalent of dihalocarbene, KMnO4 or m-CPBA gives regio- and stereospecifically one product resulting from the attack of the C6-C7 double bond. The molecular Structure Shows that this attack occurs on the a face of this double bond. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：6645 / 6648
页数：4
相关论文
共 50 条
12345