Oxidation and addition of Dihalocarbenes to β-himachalene

被引：51

作者：

Eljamili, H

Auhmani, A ^{[1
]}

Dakir, M

Lassaba, E

Benharref, A

Pierrot, M

Chiaroni, A

Riche, C

机构：

[1] Fac Sci Semlalia, Dept Chim, Lab Chim Subst Nat & Heterocycles, Marrakech, Morocco

[2] ICSN, CNRS, F-91198 Gif Sur Yvette, France

[3] Ctr Sci St Jerome, LBS UMR 6517 2, F-13397 Marseille 20, France

来源：

TETRAHEDRON LETTERS | 2002年 / 43卷 / 37期

关键词：

D O I：

10.1016/S0040-4039(02)01407-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reaction of beta-himachalene with one equivalent of dihalocarbene, KMnO4 or m-CPBA gives regio- and stereospecifically one product resulting from the attack of the C6-C7 double bond. The molecular Structure Shows that this attack occurs on the a face of this double bond. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：6645 / 6648

页数：4

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